马氏体晶体位错结构中的长程有序

Faina Fedorovna Satdarova
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摘要

对物体上的衍射观测的最优估计可靠地检测到马氏体相变中位错结构的周期性,作为其波动性的展示。沿滑移面法向的周期与晶体中位错环的半径相当。测得环路排列的一维长程有序度接近等于统一的上限。根据金属理论,所观察到的结构可能是由量子晶格振动产生的,这种振动驱动了一个跳跃式的相变。存在一个简单的解释:在温度急剧下降后,传导电子的过剩能量导致晶体在平移对称的转变下立即膨胀。由电子-声子相互作用引起的晶格内部位移同时触发了周围基体中薄马氏体板形成的波动过程,这在金相学中被观察到。在深入分析马氏体晶体位错结构的基础上,提出了马氏体相变是一种宏观的量子现象,与金属晶体系统的对称性有关的物理概念。
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Long-Range Order in the Dislocation Structure of Martensite Crystals
Optimal estimation of the diffraction observations over the object reliably detects periodicity in the dislocation structure of martensitic transformation as an exhibition of its wave nature. The period along normal to the slip planes is comparable with the radius of dislocation loops in crystals. The measured degree of one-dimensional long-range order in the arrangement of the loops is close to the upper limit equal to unity. Subject to the theory of metals, the observed structure could be generated by quantum lattice vibrations, which actuate a jump-like phase transition. A simple explanation exists: after a sharp fall in temperature, the excess energy of conduction electrons causes the crystal to expand instantly with the transformation of translational symmetry. Internal shifts of the crystal lattice caused by electron-phonon interactions concurrently trigger the wave process of formation of thin martensitic plates in the surrounding matrix, which are observed in metallography. Based on an in-depth analysis of the dislocation structure of martensite crystals, a physically founded concept is advanced in which the martensitic transformation is a macroscopic quantum phenomenon connected with the symmetry properties of a crystal system in metals.
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