b2型合金的有序动力学行为

Y. Tahara, K. Oki, 田原 良信, 沖 憲典, ヨシノブ タハラ, ケンスケ オオキ
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引用次数: 0

摘要

从理论和实验两方面研究了b2型FeCo合金的有序动力学。B2型有序的动力学方程一般由B2型结构中两个子晶格之间的对称性和平衡态的稳定性这两个物理条件推导而来。具有三阶有序度项的一般动力学方程具有形式简单、通用性强的优点,适用于分析b2型合金的有序动力学行为。用x射线衍射观察了等原子FeCo合金等温有序时晶格常数的变化,并用动力学方程进行了分析。方程能较好地再现823K以上晶格常数的等温变化,但在773K以下晶格常数的等温变化不能令人满意,特别是在退火初期观察到的晶格常数的两步变化。这两步变化可以用包含空位浓度的扩展动力学方程很好地解释。测定了FeCo合金中空位形成能为91 kJ/mol,空位迁移能为139 kJ/mol。
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Kinetic Behavior of Ordering in B2-type Alloys
Kinetics of ordering in B2-type FeCo alloy was investigated both experimentally and theoretically. Kinetic equation for B2-type ordering was generaily derived from the two physical conditions, namely the symmetry between two sublattices in the B2--type structure and the stability of the equilibrium state. The general kinetic equation with third order term of the degree of order has an advantage over the others in that it is simpler in form and more general, and it is applicable to the analysis of the kinetic behavior on ordering in B2-type alloys. The variation of lattice constant on isothermal ordering for the equiatomic FeCo alloy was observed by X-ray` diffraction, and analyzed using present kinetic equation. Isothermal change of lattice constant above 823K was reproduced well by the equation, but not satisfactorily below 773K, particularly about a two-step change of lattice constant observed at an early stage of annealing. This two--step change was interpreted very well by the extended kinetic equation containing the vacancy concentration. The values for the formation and migration energies of vacancies in the FeCo alloy were determined as 91 and 139 kJ/mol, respectively.
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