芳香植物作为干燥物的吸附和热力学性质

Yurii Sniezhkin, N.О. Dabizha, N. Dmytrenko, N. Malashchuk
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引用次数: 0

摘要

生物技术、化妆品、制药和食品行业对芳香草药的高需求导致对加工芳香原料以保存生物活性物质和精油的技术过程的要求增加。薄荷(Mentha piperita L.)是一种著名的药用精油作物,广泛分布在乌克兰各地。由于其有益的特性和对人体的治疗作用,它被广泛使用。本文的目的是研究芳香植物的吸附和热力学性质,以确定干燥和储存过程的工艺参数,以确保最小的比能量消耗和最大限度地保存精油。介绍了薄荷叶吸附性能的研究结果。采用标准的静态失重法测定了薄荷叶在30、40、50℃三种不同温度下的吸附水分等温线。利用克劳修斯-克拉珀龙方程,从水分等温线计算净等等吸附热。利用差示蒸发微热量计,实验得到了40和50ºС下薄荷叶干燥的比热耗。揭示了薄荷精油挥发性物质对汽化热的影响。芳香植物干燥温度的选择主要取决于精油的热敏性。干燥温度对薄荷叶中挥发性芳香族化合物去除率的影响研究表明,物料在脱水过程中的最高允许温度不应超过薄荷醇的熔点42.5ºС。
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SORPTION AND THERMODYNAMIC PROPERTIES OF AROMATIC PLANTS AS DRYING OBJECTS
The high demand for aromatic herbs in the biotechnological, cosmetic, pharmaceutical and food industries led to increased requirements for the technological processes of processing aromatic raw materials to preserve biologically active substances and essential oils. Peppermint (Mentha piperita L.) is a well-known medicinal essential oil crop that is widely distributed throughout Ukraine. It is widely used due to its beneficial properties and therapeutic effect on the human body. The purpose of the article is studies of sorption and thermodynamic properties of aromatic plants to determine technological parameters of drying and storage processes, which ensure minimum specific energy consumption and maximum preservation of essential oils. The results of study on sorption properties of peppermint leaves are presented. Adsorption moisture isotherms of peppermint leaves were determined at three different temperatures 30, 40 and 50 ºC, using the standard gravimetric static method. The net isosteric heat of adsorption was calculated from moisture isotherms, using the Clausius-Clapeyron equation. The specific heat consumption for drying peppermint leaves at temperatures of 40 and 50 ºС was obtained experimentally, using the differential microcalorimeter of evaporation. The effect of volatile substances of peppermint essential oil on the heat of vaporization was revealed. The choice of drying temperature of aromatic plants is primarily determined by the thermal sensitivity of essential oils. The study of the effect of drying temperature on the removal of volatile aromatic compounds from peppermint leaves showed that the maximum allowable temperature of the material during dehydration should not exceed the melting point of menthol at 42,5 ºС.
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