发光器件SiGeSn/GeSn异质结构的应变工程(会议报告)

D. Buca, D. Gruetzmacher, M. E. Kurdi, D. Stange, Z. Ikonić, N. V. D. Driesch, D. Rainko, H. Sigg, J. Hartmann
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摘要

讨论了GeSn作为实现集成在硅片上的第四组光源梦想的解决方案。在Ge晶格中加入Sn降低了导带能量,导致直接带隙半导体带结构。然而,压缩应变增加了GeSn块体的直接能带能,使其Sn含量增加。尽管在Si上生长外延GeSn合金有许多困难,但可以实现数百nm厚的GeSn层,各种Sn浓度高达15%,并可作为激光器的增益材料。目前的研究主要集中在将锡含量提高到20%和结构布局上。这里的挑战是在高锡含量时质量下降,并且在与Ge/Si界面形成的雾中隔离了有源层,从而增加了激光阈值。在这个方向上,我们讨论了不同量子阱厚度对MQW SiGeSn/GeSn异质结构的激光和阈值的影响。另一种解决方案是通过引入Si3N4应力源和绝缘子上的GeSn技术,将本征应变类型从压缩转变为拉伸。这些方法在CMOS技术中是众所周知的,可以应用于非常低Sn含量的GeSn合金。从理论和实验两方面讨论了达到室温激光的最佳途径。
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Strain engineering in SiGeSn/GeSn heterostructures for light emitters (Conference Presentation)
GeSn is discussed as solution to realize the dream of a group IV light source integrated on a Si chip. Sn added into a Ge lattice decreases the conduction band energies leading to a direct bandgap semiconductor band structure. However, the compressive strain increases the direct band energy imposing a large Sn content in the GeSn bulk. In spite of many difficulties regarding the growth of epitaxial GeSn alloys on Si, several hundred nm thick GeSn layers with various Sn concentrations up to 15% could be realized and used as gain material for lasers. Nowadays research concentrates on increasing the Sn content towards 20 at% as well as structural layout. The challenge here is the decreasing quality at high Sn contents and the isolation of the active layer from the mists formed at the interface with Ge/Si which increase the laser threshold. In this direction we discuss the influence on lasing and threshold of MQW SiGeSn/GeSn heterostructures with different quantum well thicknesses. Other solution proposed is the change of intrinsic strain type from compressive into tensile by introducing Si3N4 stressors and also GeSn on Insulator technology. These methods are well known in CMOS technology and can be applied to very low Sn content GeSn alloys. The discussion on the best way to reach room temperature laser is addressed both theoretical and experimental.
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