原子吸收光谱法和中子活化分析法测定煤样品中主要和痕量/有毒金属

M. A. Rauf, M. Ikram, N. Ayub
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引用次数: 8

摘要

摘要采用原子吸收光谱和中子活化分析两种分析技术,对巴基斯坦不同地区的20个采煤样品和当地市场的6个木煤样品进行了有毒/微量元素浓度分析。原子吸收光谱法测定了Ca、Cr、Fe、Mg、Ni、Pb、Zn等7种金属,NAA法测定了Ce、Co、Cr、Cs、Eu、Fe、Hf、Mn、Na、Sb、Sc、Rb、Tb、Th、Yb、Zn等16种元素。在采煤样品中观察到S、Cr、Fe和Na等有毒元素的显著浓度,这可能给火电厂带来环境和工程/运营问题。
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DETERMINATION OF MAJOR AND TRACE/TOXIC METALS IN COAL SAMPLES BY ATOMIC ABSORPTION SPECTROSCOPY AND NEUTRON ACTIVATION ANALYSIS
ABSTRACT Twenty mined coal samples obtained from different areas of Pakistan and six wooden coal samples obtained from local market were analyzed for toxic/trace element concentration by two analytical techniques namely atomic absorption spectroscopy and neutron activation analysis. Seven metals, i.e., Ca, Cr, Fe, Mg, Ni, Pb and Zn were determined by AAS whereas 16 elements namely, Ce, Co, Cr, Cs, Eu, Fe, Hf, Mn, Na, Sb, Sc, Rb, Tb, Th, Yb and Zn were determined by NAA in all samples. Significant concentration of toxic elements such as S, Cr, Fe and Na were observed in mined coal samples, which may pose environmental and engineering/operational problems for thermal power plants.
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