{"title":"氧化铝负载的氮化钼催化剂上咔唑的加氢脱氮","authors":"M. Nagai, T. Miyao, S. Omi","doi":"10.1201/9781482273540-19","DOIUrl":null,"url":null,"abstract":"This paper reports an experimental study of hydrodenitrogenation, at 330-350 °C and 50-150 atm total pressure, of carbazole on alumina-supported molybdenum nitride catalyst. The kinetics of C-N hydrogenolysis is analyzed to obtain rate expression for C-N hydrogenolysis which is a rate-determining step in equilibrium of the hydrogenation. Rate equations of the Langmuir-Hinshelwood type were compared with the rate dat using a non-linear leat-squares regression technique.","PeriodicalId":20402,"journal":{"name":"Preprints-American Chemical Society Division of Petroleum Chemistry","volume":"3 1","pages":"577-583"},"PeriodicalIF":0.0000,"publicationDate":"1994-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Hydrodenitrogenation of carbazole on alumina-supported molybdenum nitride catalyst\",\"authors\":\"M. Nagai, T. Miyao, S. Omi\",\"doi\":\"10.1201/9781482273540-19\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This paper reports an experimental study of hydrodenitrogenation, at 330-350 °C and 50-150 atm total pressure, of carbazole on alumina-supported molybdenum nitride catalyst. The kinetics of C-N hydrogenolysis is analyzed to obtain rate expression for C-N hydrogenolysis which is a rate-determining step in equilibrium of the hydrogenation. Rate equations of the Langmuir-Hinshelwood type were compared with the rate dat using a non-linear leat-squares regression technique.\",\"PeriodicalId\":20402,\"journal\":{\"name\":\"Preprints-American Chemical Society Division of Petroleum Chemistry\",\"volume\":\"3 1\",\"pages\":\"577-583\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1994-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Preprints-American Chemical Society Division of Petroleum Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1201/9781482273540-19\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Preprints-American Chemical Society Division of Petroleum Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1201/9781482273540-19","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Hydrodenitrogenation of carbazole on alumina-supported molybdenum nitride catalyst
This paper reports an experimental study of hydrodenitrogenation, at 330-350 °C and 50-150 atm total pressure, of carbazole on alumina-supported molybdenum nitride catalyst. The kinetics of C-N hydrogenolysis is analyzed to obtain rate expression for C-N hydrogenolysis which is a rate-determining step in equilibrium of the hydrogenation. Rate equations of the Langmuir-Hinshelwood type were compared with the rate dat using a non-linear leat-squares regression technique.
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