{"title":"同步加速器x射线粉末衍射研究life5o8 - lial5o8尖晶石固溶体的溶解度","authors":"J. Darul, W. Nowicki, P. Piszora, E. Wolska","doi":"10.1524/ZKSU.2007.2007.SUPPL_26.471","DOIUrl":null,"url":null,"abstract":"The formation of substitutional solid solutions between the isostructural LiFe5O8 and LiAl5O8 was studied by synchrotron X-ray powder diffraction from room temperature up to 900°C. Structural characterization and distribution of cations in the A and B spinel sublat- tices for LiFe2.5Al2.5O8 were obtained by Rietveld structure refinement. We report new re- sults on the solubility limits in the LiFe5O8-LiAl5O8 system. The \"iron-rich\" (LiAl1.2Fe3.8O8) and \"aluminum-rich\" (LiFe1.2Al3.8O8) solid solutions coexisted during the thermal treatment up to 900°C, and the formation of single-phase spinel solid solution was not observed.","PeriodicalId":23897,"journal":{"name":"Zeitschrift Fur Kristallographie","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2007-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Synchrotron X-ray powder diffraction studies of solubility limits in the LiFe5O8-LiAl5O8spinel solid solutions\",\"authors\":\"J. Darul, W. Nowicki, P. Piszora, E. Wolska\",\"doi\":\"10.1524/ZKSU.2007.2007.SUPPL_26.471\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The formation of substitutional solid solutions between the isostructural LiFe5O8 and LiAl5O8 was studied by synchrotron X-ray powder diffraction from room temperature up to 900°C. Structural characterization and distribution of cations in the A and B spinel sublat- tices for LiFe2.5Al2.5O8 were obtained by Rietveld structure refinement. We report new re- sults on the solubility limits in the LiFe5O8-LiAl5O8 system. The \\\"iron-rich\\\" (LiAl1.2Fe3.8O8) and \\\"aluminum-rich\\\" (LiFe1.2Al3.8O8) solid solutions coexisted during the thermal treatment up to 900°C, and the formation of single-phase spinel solid solution was not observed.\",\"PeriodicalId\":23897,\"journal\":{\"name\":\"Zeitschrift Fur Kristallographie\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2007-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeitschrift Fur Kristallographie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1524/ZKSU.2007.2007.SUPPL_26.471\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Chemistry\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift Fur Kristallographie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1524/ZKSU.2007.2007.SUPPL_26.471","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Chemistry","Score":null,"Total":0}
Synchrotron X-ray powder diffraction studies of solubility limits in the LiFe5O8-LiAl5O8spinel solid solutions
The formation of substitutional solid solutions between the isostructural LiFe5O8 and LiAl5O8 was studied by synchrotron X-ray powder diffraction from room temperature up to 900°C. Structural characterization and distribution of cations in the A and B spinel sublat- tices for LiFe2.5Al2.5O8 were obtained by Rietveld structure refinement. We report new re- sults on the solubility limits in the LiFe5O8-LiAl5O8 system. The "iron-rich" (LiAl1.2Fe3.8O8) and "aluminum-rich" (LiFe1.2Al3.8O8) solid solutions coexisted during the thermal treatment up to 900°C, and the formation of single-phase spinel solid solution was not observed.
期刊介绍：
Zeitschrift für Kristallographie International journal for structural, physical, and chemical aspects of crystalline materials ISSN 0044-2968 Founded in 1877 by Paul Groth Zeitschrift für Kristallographie is one of the world’s oldest scientific journals. In original papers, letters and review articles it presents results of theoretical or experimental study on crystallography.
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