利用不同功能块构建具有磁性和荧光的半双各向异性导电双面结构膜

Yunrui Xie, H. Qi, Q. Ma, Li Dan, Wensheng Yu, Guixia Liu, Xiang-ting Dong
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引用次数: 0

摘要

提出了基于模块化设计的半双向异性电导率的新概念。通过调整具有各向异性电导率的两个表面的面积,使材料一半具有双各向异性电导率,另一半具有单各向异性电导率。采用静电纺丝法制备了具有磁性和荧光特性的半双各向异性双面导电膜。将C-R块(上)、M-G块和C-R块(下)组装成SCMF。选择双面结构的纳米带作为建筑单元来获得微分区。模块化结构进一步防止了各种功能物质之间的负相互作用。SCMF具有双色发光和可变磁性。SCMF获得了调谐后的半双各向异性导电性,其中具有单导电性各向异性的C-R块(上)的面积是具有单导电性各向异性的C-R块(下)的一半,因此一半的SCMF具有双导电性各向异性,另一半SCMF具有单导电性各向异性。
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Construction of Semi-Bianisotropic Conductive Janus-Structure Membrane Offering Magnetism and Fluorescence by Utilizing Different Functional Blocks
A new concept of semi-bianisotropic conductivity is put forward based on modularization design. Half of the material has dual anisotropic conductivity while the other half has single anisotropic conductivity by adjusting areas of the two surfaces endowed with anisotropic conductivity and vertically arranged up to down. Semibianisotropic conductive Janus-structure membrane affording magnetism and fluorescence (SCMF) is prepared by constructing three blocks via electro-spinning. Three blocks, including C-R block (top), M-G block and C-R block (down), are assembled into SCMF. Janus-structure nanobelts are selected as building units to gain micro zoning. Modular structure further prevents negative interactions among various functional substances. SCMF has bicolor luminescence and variable magnetism. SCMF gains tuned semi-bianisotropic conductivity, where the area of C-R block (top) with single conductive aeolotropism is half of C-R block (down) with single conductive aeolotropism, so half of SCMF has double conductive aeolotropism and other half of SCMF has single conductive aeolotropism.
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