利用铁和镁生产废水去除工业废水中的铜离子

IF 0.2 Q4 FORESTRY Lesnoy Zhurnal-Forestry Journal Pub Date : 2023-04-25 DOI:10.21440/0536-1028-2023-2-32-42
A. Sobenin, N. Antoninova, A. Usmanov, Kseniia Shepel
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引用次数: 0

摘要

研究目的是评估利用铁和镁生产废水去除工业废水中铜离子的可能性。研究方法。以铁镁生产废液为原料,对工业废水溶液中的铜离子进行了去除试验。获得的数据显示了废水溶液中所研究金属离子含量的变化。进行理论研究,分析现有污水处理方法的有效性,对研究结果进行研究和推广。用瓦里安AA 240 FS原子吸收分光光度计测定溶液中金属离子的初始浓度,采用氘灯进行背景校正和火焰喷涂。用Hanna HI 99121便携式pH计测量温度和pH值。固体样品的矿化用MARS 5消解微波系统在Easy Prep容器中添加硝酸和氢氟酸进行。结果。利用铁镁生产废渣去除工业废水中的铜离子的研究结果表明,所研究的样品能有效地吸附水溶液中的铜离子。结果表明,滤液中铜的含量随所测吸附剂样品的重量而变化。随着样品加药率从0.2 g增加到0.5 g,第1组和第2组的污染物萃取度指标分别从52.02增加到99.04%和43.2%增加到98.91%。静态体积容量的指标也取决于加入到溶液中的样品的质量,并随着加药速率的增长而降低。铁镁生产的废料中含有高浓度的镁和铁。在与工业废水相互作用后,它们主动将镁释放到溶液中,但继续从中提取铁。无论样品质量如何,溶液中污染物的萃取程度和铁的静态体积容量的指标在99.85 ~ 99.98%和3.9 ~ 10.82 mg/g之间都有很高的值。结果范围。所得数据将用于开发消除水体污染的有效材料和方法。
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Removal of copper ions from industrial wastewater using waste from iron and magnesium production
Research objective is to assess the possibility of removing copper ions from industrial wastewater using waste from iron and magnesium production. Methods of research. An experiment was conducted to remove copper ions from a solution of industrial wastewater using waste from iron and magnesium production. Data were obtained showing changes in the ion content of the studied metals in wastewater solutions. Theoretical research was carried out to analyze the effectiveness of existing wastewater treatment methods in order to study and generalize the results. The initial concentration of metal ions in solutions was measured with a Varian AA 240 FS atomic absorption spectrophotometer with a deuterium lamp for background correction and flame spraying. Temperature and pH were measured with a Hanna HI 99121 portable pH meter. Mineralization of solid samples was carried out with a MARS 5 Digestion Microwave System in Easy Prep vessels with the addition of nitric and hydrofluoric acids. Results. The results of the research on the removal of copper ions from industrial waste water using iron-magnesium production waste show that the samples under investigation were effective in absorbing copper from aqueous solutions. It was found that the amount of copper in the filtrates varies depending on the tested sorbent sample weight. There is an increase in the indicator of the degree of pollutant extraction from solutions from 52.02 to 99.04% for group 1 and from 43.2 to 98.91 % for group to respectively with an increase in the sample dosing rate from 0.2 to 0.5 g. The indicator of static volume capacity also depends on the mass of the sample added to the solution and decreases with the dosing rate growth. Wastes of iron-magnesium production contain magnesium and iron in high concentrations. After interaction with industrial waste water, they actively release magnesium into the solution, but continue to extract iron from it. The indicators of the degree of pollutant extraction from solutions and of static volume capacity for iron have high values regardless of the sample weight for both groups and vary from 99.85 to 99.98% and from 3.9 to 10.82 mg/g. Scope of results. The data obtained will used to develop effective materials and methods for water bodies pollution elimination.
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