AQUA:行星模型的水状态方程集合

J. Haldemann, Y. Alibert, C. Mordasini, W. Benz
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引用次数: 21

摘要

水是行星结构建模中的关键化学元素之一。由于相图复杂,状态方程往往只涵盖了行星模型所需的部分压力-温度空间。我们建立了一个H$_2$O的状态方程,它的范围从0.1 Pa到400tpa,从150k到$10^{5}$ K,可以用来模拟行星内部。我们将在局部区域有效的状态方程结合起来,形成一个跨越所述压力和温度范围的连续状态方程。我们提供了最重要的热力学量的表格值,即密度、绝热温度梯度、熵、内能和水在此压力和温度范围内的声速。为了更好的可用性,我们还计算了密度-温度和密度-内部能量网格。我们进一步讨论了这种状态方程对行星质量半径关系的影响,并与其他流行的状态方程如ANEOS和QEOS进行了比较。AQUA是对行星模型有用的现有状态方程的组合。我们表明,AQUA在大多数地区是水的热力学一致描述。在高于10gpa的压力下,AQUA预测的系统密度大于ANEOS或QEOS。在先前提出的状态方程中已经存在的特征,这是这项工作的主要基础方程。我们表明,状态方程的选择对质量-半径关系有很大的影响,这突出了状态方程领域和高压水实验数据的未来发展的重要性。
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AQUA: a collection of H2O equations of state for planetary models
Water is one of the key chemical elements in planetary structure modelling. Due to its complex phase diagram, equations of state cover often only parts of the pressure - temperature space needed in planetary modelling. We construct an equation of state of H$_2$O spanning a very wide range from 0.1 Pa to 400 TPa and 150 K to $10^{5}$ K, which can be used to model the interior of planets. We combine equations of state valid in localised regions to form a continuous equation of state spanning over said pressure and temperature range. We provide tabulated values for the most important thermodynamic quantities, i.e., density, adiabatic temperature gradient, entropy, internal energy and bulk speed of sound of water over this pressure and temperature range. For better usability we also calculated density - temperature and density - internal energy grids. We discuss further the impact of this equation of state on the mass radius relation of planets compared to other popular equation of states like ANEOS and QEOS. AQUA is a combination of existing equation of state useful for planetary models. We show that AQUA is in most regions a thermodynamic consistent description of water. At pressures above 10 GPa AQUA predicts systematic larger densities than ANEOS or QEOS. A feature which was already present in a previously proposed equation of state, which is the main underlying equation of this work. We show that the choice of the equation of state can have a large impact on the mass-radius relation, which highlights the importance of future developments in the field of equation of states and regarding experimental data of water at high pressures.
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