水葫芦活性炭吸附六价铬的动力学及等温线研究

IF 1 Q4 CHEMISTRY, MULTIDISCIPLINARY Chemistry & Chemical Technology Pub Date : 2021-02-15 DOI:10.23939/CHCHT15.01.001
Angelica Angeles Macalalad, Quennie Rose Ebete, Dominic Gutierrez, Madelaine Ramos, B. J. A. Magoling
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引用次数: 2

摘要

本文主要研究了水葫芦活性炭(WH-AC)作为吸附剂去除水溶液中的铬(VI)。优化后的WH-AC为介孔颗粒状。在11.564 m2/g的表面积上发现其具有良好的吸附能力。优化后的WH-AC吸附数据符合准二级动力学和Freundlich等温模型。根据拟二级动力学模型得到的相关系数,R2值均在0.99以上,更接近于1(1)的单位,说明其发生了化学吸附过程。当吸附浓度从20 mg/l增加到50 mg/l时,WH-AC的吸附量从1.98 mg/g增加到4.68 mg/g。研究结果表明,水葫芦活性炭对六价铬的吸附是一种有效的替代技术。
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Kinetics and Isotherm Studies on Adsorption of Hexavalent Chromium Using Activated Carbon from Water Hyacinth
The present study is focused on the use of activated carbon derived from water hyacinth (WH-AC) as adsorbent for the removal of Cr(VI) from aqueous solution. The optimized WH-AC was found to be mesoporous and considered as granular. The surface area of 11.564 m2/g was found to have a good adsorption capacity. The adsorption data of the optimized WH-AC followed a pseudo-second order kinetics and the Freundlich isotherm model. Based on the correlation coefficient obtained from pseudo-second-order kinetic model, the R2 values were all above 0.99, which is closer to unity of one (1) indicating that it followed a chemisorption process. The adsorption capacity of WH-AC increased from 1.98 to 4.68 mg/g when adsorbate concentration increased from 20 to 50 mg/l. The overall study proved that the adsorption by activated carbon derived from water hyacinth can be an alternative and efficient technique in hexavalent chromium removal.
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来源期刊
Chemistry & Chemical Technology
Chemistry & Chemical Technology CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
1.70
自引率
44.40%
发文量
60
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