α-磺基自由基的断裂:有机合成的通用过程

Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry Pub Date : 2001-07-01 DOI:10.1016/S1387-1609(01)01270-1

Frédérique Bertrand , Frédéric Le Guyader , Lucia Liguori , Gilles Ouvry , Béatrice Quiclet-Sire , Stéphanie Seguin , Samir Z. Zard

{"title":"α-磺基自由基的断裂:有机合成的通用过程","authors":"Frédérique Bertrand , Frédéric Le Guyader , Lucia Liguori , Gilles Ouvry , Béatrice Quiclet-Sire , Stéphanie Seguin , Samir Z. Zard","doi":"10.1016/S1387-1609(01)01270-1","DOIUrl":null,"url":null,"abstract":"<div><p>The reversible addition of aliphatic radicals to sulphur dioxide can be exploited to design a variety of tin-free chain reactions. This brief review summarises some of the possibilities, namely radical allylation, vinylation, alkynylation, and azidation of various substrates.</p></div>","PeriodicalId":100305,"journal":{"name":"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry","volume":"4 7","pages":"Pages 547-555"},"PeriodicalIF":0.0000,"publicationDate":"2001-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1387-1609(01)01270-1","citationCount":"9","resultStr":"{\"title\":\"α-Scission of sulfonyl radicals: a versatile process for organic synthesis\",\"authors\":\"Frédérique Bertrand , Frédéric Le Guyader , Lucia Liguori , Gilles Ouvry , Béatrice Quiclet-Sire , Stéphanie Seguin , Samir Z. Zard\",\"doi\":\"10.1016/S1387-1609(01)01270-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The reversible addition of aliphatic radicals to sulphur dioxide can be exploited to design a variety of tin-free chain reactions. This brief review summarises some of the possibilities, namely radical allylation, vinylation, alkynylation, and azidation of various substrates.</p></div>\",\"PeriodicalId\":100305,\"journal\":{\"name\":\"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry\",\"volume\":\"4 7\",\"pages\":\"Pages 547-555\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1387-1609(01)01270-1\",\"citationCount\":\"9\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1387160901012701\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387160901012701","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 9

摘要

脂肪族自由基对二氧化硫的可逆加成可用于设计各种无锡链式反应。这篇简短的综述总结了一些可能性，即自由基烯丙基化、乙烯基化、炔基化和各种底物的叠氮化。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

α-Scission of sulfonyl radicals: a versatile process for organic synthesis

The reversible addition of aliphatic radicals to sulphur dioxide can be exploited to design a variety of tin-free chain reactions. This brief review summarises some of the possibilities, namely radical allylation, vinylation, alkynylation, and azidation of various substrates.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry

自引率

0.00%

发文量