二氧化钛和氧化锌纳米颗粒:工业废水的合成、表征和光催化作用

Naiara Maria Pavani, D. A. Macena, Jacqueline Roberta Tamashiro, L. H. C. Silva, Maryane Pipino Beraldo Almeida, A. Kinoshita
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引用次数: 0

摘要

废水的再利用是实现更可持续发展的主要挑战之一。纺织工业的染料会渗透、污染土壤并影响河道。先进的氧化过程(AOP),如紫外光辐射和金属纳米颗粒的多相光催化,产生活性氧和羟基自由基,可以减少废水污染物。本文合成了氧化锌(ZnO-NP)和二氧化钛(TiO2-NP)纳米颗粒,用于光降解亚甲基蓝和酒黄染料。利用x射线衍射和高分辨率扫描电镜对纳米颗粒进行了晶体学和形态学表征。合成过程产生了纳米粒子。TiO2-NP对亚甲基蓝染料的去除率为82% ~ 85%,而ZnO-NP对酒黄石染料的去除率为79.6%。结果表明,纳米颗粒与POA复合是光催化降解染料的有效替代材料。
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NANOPARTÍCULAS DE DIÓXIDO DE TITÂNIO E ÓXIDO DE ZINCO: SÍNTESE, CARACTERIZAÇÃO E AÇÃO FOTOCATALÍTICA EM EFLUENTES INDUSTRIAIS
The reuse of effluent water is one of the main challenges to achieve a more sustainable development. Dyes from the textile industry can percolate, contaminate soils and affect water courses. Advanced Oxidative Processes (AOP), such as heterogeneous photocatalysis with UV light radiation and metallic nanoparticles, generate reactive oxygen species and hydroxyl radicals that can reduce effluent pollutants. This work synthesized zinc oxide (ZnO-NP) and titanium dioxide (TiO2-NP) nanoparticles in order to photodegrade methylene blue and tartrazine yellow dyes. The crystallographic and morphological characterization of the nanoparticles was performed by X-ray diffraction and high resolution scanning electron microscopy. The syntheses produced nanometric particles. The methylene blue dye had greater degradation by TiO2-NP (82 to 85%), whereas the tartrazine yellow dye with ZnO-NP (79.6% removal). It is concluded that the nanoparticles combined with POA are an effective alternative for the photocatalytic degradation of dyes.
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