Fabrication of 1T VS2 Electrode‐Based In‐Plane Micro‐Supercapacitor Using a Cost‐Effective Mask‐Assisted Printing Technique

Vanadium disulfide (VS2) is an important member of the transition‐metal dichalcogenides (TMDs) family, which offers high conductivity. In nature, it can exist in two phases, i.e., 1T and 2H. Herein, the metallic 1T VS2‐based in‐plane micro‐supercapacitor (MSC) is fabricated by a facile‐mask‐assisted printing technique. Initially, the 1T VS2 nanosheets are synthesized using a simple one‐pot hydrothermal route. The material characterizations have claimed the formation of a 1T phase and the density of states (DOS) reveal that the 1T phase of VS2 is metallic in nature. After experimental and theoretical investigations of synthesized nanosheets, a VS2 electrode‐based in‐plane MSC is fabricated using a simple mask‐assisted printing technique. The fabricated device demonstrates excellent capacitance retention of 97.6% after 1000 cycles of cyclic voltammetry measurement at a 100 mV s−1 scan rate. The device also shows an excellent areal capacitance of 212.7 mF cm−2 and a high areal energy density of 10.63 μWh cm−2 at a high‐power density of 4.45 mW cm−2. This low‐cost and simple fabrication process can produce high‐performance in‐plane MSC devices.