乳化和界面张力提升对表面活性剂驱提高采收率的作用

Xiaoxiao Li, X. Yue, Jirui Zou, Li-juan Zhang, K. Tang
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摘要

本文首先设计了人工油膜的可视化物理模型,研究了人工油膜的位移机理。通过大量对比实验,探讨了不同流体介质中不同流量下油膜的剥离机理及采油性能。此外,对油膜的影响因素进行了综合评价,主要包括:流量、表面活性剂行为和原油粘度。结果表明:(1)无论原油粘度如何,流量对油膜剥离的贡献有限,最终油膜置换效率的最大值仅为10%左右;(2)表面活性剂驱油对油膜驱替在界面张力(ITF)降低和乳化能力两方面具有协同作用。两种油样在所有运行中表现最为突出,超低值IFT的降低并不是影响油膜置换效率的唯一决定性因素,乳化能力对油膜的剥离起着关键作用,这是由于乳化和分散对油膜的影响;(3)表面活性剂驱流量的增加能够增强油膜的剥离,但对最终油膜驱替效率有客观影响;(4)流量对油膜剥离的影响很大,但最容易控制的因素是表面活性剂的性质。这一发现为油膜剥离和表面活性剂选择提高采收率提供了依据。
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The Role of Emulsification and Interfacial Tension Ift For the Enhanced Oil Recovery Eor in Surfactant Flooding
In this study, a visualized physical model of artificial oil film was firstly designed to investigate the oil film displacement mechanisms. Numerous comparative experiments were conducted to explore the detachment mechanisms of oil film and oil recovery performances in different fluid mediums with flow rate. In addition, the of influencing factors of oil film were comprehensively evaluated, which mainly includes: flow rate, surfactant behaviors, and crude oil viscosity. The results show that, (1) regardless of the viscosity of crude oil, flow rate presents a limited contribution to the detachment of oil film and the maximum of ultimate oil film displacement efficiency is only approximately 10%; (2) surfactant flooding has a synergistic effect on the oil film displacement on two aspects of interfacial tension (ITF) reduction and emulsifying capacity. Giving the most outstanding performance for two oil samples in all runs, IFT reduction of ultra-low value is not the only decisive factor affecting oil film displacement efficiency, but the emulsifying capability plays the key role to the detachment of oil film due to effect of emulsifying and dispersing on oil film; (3) the increasing flow rate of surfactant flooding is able to enhance the detachment of oil film but has an objective effect on the final oil film displacement efficiency; (4) flow rate have the much influence on the detachment of oil film, but the most easily controlled factor is the surfactant property. The finding provides basis for oil film detachment and surfactant selection EOR application.
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