MgO负载Al2O3氧化物:一种新型、高效、可重复使用的查尔酮合成催化剂

Santosh S. Katkar, A. H. Kategaonkar, Kaluram N. Vidhate
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引用次数: 1

摘要

用一种简单的共沉淀法研究了一系列Mg-Al混合金属氧化物。采用XRD、SEM、EDS、TEM、BET、CO2-TPD等表征手段对其理化性质进行了表征。在乙醇回流条件下,使用镁铝氧化物合成不同醛和苯乙酮的查尔酮的高效和简便的方案得到了良好的收率。催化剂的可回收性是本协议的一个重要特点。此外,还提出了MgO的分散作用,提高了碱度、孔径和催化活性。
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MgO Supported Al2O3 Oxide: A New, Efficient, and Reusable Catalyst for Synthesis of Chalcones
We have studied a series of mixed metal oxides of Mg-Al by a simple co-precipitation technique. Various characterization techniques, including XRD, SEM, EDS, TEM, BET and CO2-TPD were carried out to investigate their physicochemical properties. An efficient and facile protocol has been documented for the synthesis of chalcones using different aldehydes and acetophenone using Mg-Al oxide under reflux conditions in ethanol affording good to excellent yields. Recyclability of a catalyst is a significant feature of this protocol. Moreover, it was proposed that MgO can disperse and increase the basicity, pore size and catalytic activity.
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