模拟烃溶液中合成镍化合物在铁矿精矿和灰渣材料上的吸附

N. Manchuk, I. Denysiuk
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引用次数: 0

摘要

在己烷介质中,研究了从烃类(环烷酸盐和乙酰丙酮酸镍)标准化测试溶液中吸附合成镍化合物。合成镍化合物存在于重油、油品和重油污泥中。我们研究了利用工业废料(铁矿精矿和底灰)从标准化的烃类测试溶液中吸附镍化合物的可能性。我们还分析了以铁精矿和底灰为基础的标准化烃体系对镍的吸附等温线。我们计算了所研究的吸附剂对镍的吸附程度。研究结果可用于油品和重油污泥热吸附脱金属技术的开发,提高炼油工艺效率(提高炼油收率,减少设备腐蚀,减少裂化催化剂失活),提高油品质量。圣经12,图2。
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ADSORPTION OF SYNTHESIZED NICKEL COMPOUNDS FROM MODEL HYDROCARBON SOLUTIONS ON IRON-ORE CONCENTRATE AND ASH-SLAG MATERIAL
Adsorption of synthesized nickel compounds from standardized test solutions of hydrocarbon(naphthenate and nickel acetylacetonate (II)) has been studied in hexane medium.Synthesized nickel compounds are present in heavy oils, oil products and heavy oilsludge. We have studied the possibility for using industrial wastes (iron-ore concentrateand bottom ash) for adsorption concentration of nickel compounds from standardized testsolutions of hydrocarbon. We have also analyzed adsorption isotherm of nickel from standardized hydrocarbon systems based on iron-ore concentrate and bottom ash. We have calculated the degree of nickel adsorption from standardized hydrocarbon systems for studied adsorbents. Study results can be used for development of the technology of thermal-adsorption demetallization of oil products and heavy oil sludge that would contributeto the efficiency of oil refining processes (the increase of refinery yield, reduction of equipment corrosion and reduction in deactivation of cracking catalysts) and improvement of the quality of oil products. Bibl. 12, Fig. 2.
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