新手性萜基有机硒化合物的合成与应用

IF 1.4 4区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-01-02 DOI:10.1080/10426507.2023.2243362
Jacek Ścianowski , Agata J. Pacuła-Miszewska , Anna Laskowska , Magdalena Obieziurska-Fabisiak
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引用次数: 0

摘要

萜烯类化合物是一类重要的天然化合物,因其碳骨架结构、各种官能团的存在以及立体中心的数量而各不相同。将萜基支架与硒原子的反应活性相结合,可以获得手性和高活性化合物。有机硒衍生物作为现代有机合成中的高效试剂和催化剂,已经得到了广泛的研究。有机硒衍生物可以很容易地从目标分子中引入、操作和消除,从而为获得新化合物提供了一条有效途径。在此,我们将总结我们在设计源自单萜的手性有机硒分子及其作为试剂和催化剂的应用方面所取得的成就。
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Synthesis and applications of new chiral terpenyl organoselenium compounds

Terpenes create a substantial group of natural compounds differentiated due to the structure of the carbon skeleton, the presence of various functional groups and the number of stereogenic centers. Combining the terpenyl scaffold with the reactivity of the selenium atom enables to obtain chiral and highly reactive compounds. Organoselenium derivatives have been well-studied as efficient reagents and catalysts in modern organic syntheses. The Se-moiety can be easily introduced, manipulated and eliminated from the target molecule, thus providing an efficient route to new compounds. Herein, we will summarize our achievements in designing chiral organoselenium molecules derived from monoterpenes and their applications as reagents and catalysts.

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来源期刊
CiteScore
2.60
自引率
7.70%
发文量
103
审稿时长
2.1 months
期刊介绍: Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.
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