高分辨率电喷雾离子迁移率四极杆质谱法评价磺酰脲类除草剂

B. Clowers, W. Steiner, Heather M. Dion, L. Matz, M. Tam, E. Tarver, H. Hill
{"title":"高分辨率电喷雾离子迁移率四极杆质谱法评价磺酰脲类除草剂","authors":"B. Clowers, W. Steiner, Heather M. Dion, L. Matz, M. Tam, E. Tarver, H. Hill","doi":"10.1002/FACT.10010","DOIUrl":null,"url":null,"abstract":"The purpose of the current study was to explore and assess the potential of high resolution electrospray ionization atmospheric pressure ion mobility spectrometry (ESI–AP-IMS) as a field analytical method for the detection and identification of mixtures of sulfonylurea (SU) herbicides in aqueous samples. Because of increased usage, persistent behavior, and potential for crop damage, an environmental method of analysis capable of evaluating SU herbicides in a swift and effective manner is necessary. Eight SU herbicides were evaluated using ESI–AP-IMS quadrupole mass spectrometry. The selected herbicides were chosen based upon availability and scope of use. The SU herbicide species were qualitatively identified using quadrupole mass spectrometry, followed by the determination of reduced mobility values for characteristic ions. Various mixtures of rimsulfuron, metsulfuron-methyl, prosulfuron, sulfometuron-methyl, tribenuron-methyl, and primisulfuron-methyl could be revealed using AP-IMS. The ease of use, ability to operate under ambient conditions, and relatively rapid data acquisition times make ESI–AP-IMS an attractive candidate for the analysis of aqueous environmental field samples. © 2002 Wiley Periodicals, Inc. Field Analyt Chem Technol 5: 302–312, 2001; DOI 10.1002/fact.10010","PeriodicalId":12132,"journal":{"name":"Field Analytical Chemistry and Technology","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2001-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"18","resultStr":"{\"title\":\"Evaluation of sulfonylurea herbicides using high resolution electrospray ionization ion mobility quadrupole mass spectrometry\",\"authors\":\"B. Clowers, W. Steiner, Heather M. Dion, L. Matz, M. Tam, E. Tarver, H. Hill\",\"doi\":\"10.1002/FACT.10010\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The purpose of the current study was to explore and assess the potential of high resolution electrospray ionization atmospheric pressure ion mobility spectrometry (ESI–AP-IMS) as a field analytical method for the detection and identification of mixtures of sulfonylurea (SU) herbicides in aqueous samples. Because of increased usage, persistent behavior, and potential for crop damage, an environmental method of analysis capable of evaluating SU herbicides in a swift and effective manner is necessary. Eight SU herbicides were evaluated using ESI–AP-IMS quadrupole mass spectrometry. The selected herbicides were chosen based upon availability and scope of use. The SU herbicide species were qualitatively identified using quadrupole mass spectrometry, followed by the determination of reduced mobility values for characteristic ions. Various mixtures of rimsulfuron, metsulfuron-methyl, prosulfuron, sulfometuron-methyl, tribenuron-methyl, and primisulfuron-methyl could be revealed using AP-IMS. The ease of use, ability to operate under ambient conditions, and relatively rapid data acquisition times make ESI–AP-IMS an attractive candidate for the analysis of aqueous environmental field samples. © 2002 Wiley Periodicals, Inc. Field Analyt Chem Technol 5: 302–312, 2001; DOI 10.1002/fact.10010\",\"PeriodicalId\":12132,\"journal\":{\"name\":\"Field Analytical Chemistry and Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"18\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Field Analytical Chemistry and Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/FACT.10010\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Field Analytical Chemistry and Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/FACT.10010","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 18

摘要

本研究的目的是探索和评估高分辨率电喷雾电离大气压离子迁移谱法(ESI-AP-IMS)作为一种现场分析方法检测和鉴定水样中磺酰脲(SU)除草剂混合物的潜力。由于单硫除草剂的使用量增加、持续使用和潜在的作物危害,需要一种能够快速有效地评价单硫除草剂的环境分析方法。采用ESI-AP-IMS四极杆质谱法对8种SU除草剂进行了评价。所选择的除草剂是根据可用性和使用范围来选择的。采用四极杆质谱法对SU除草剂进行了定性鉴定,并测定了特征离子的迁移率降低值。在AP-IMS中可以发现各种环磺隆、甲磺隆、甲磺隆、甲基磺磺隆、甲基三苯脲和甲基原磺隆的混合物。易于使用,能够在环境条件下操作,以及相对快速的数据采集时间使ESI-AP-IMS成为水环境现场样品分析的有吸引力的候选者。©2002 Wiley期刊公司化学工程学报(英文版);2009;DOI 10.1002 / fact.10010
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Evaluation of sulfonylurea herbicides using high resolution electrospray ionization ion mobility quadrupole mass spectrometry
The purpose of the current study was to explore and assess the potential of high resolution electrospray ionization atmospheric pressure ion mobility spectrometry (ESI–AP-IMS) as a field analytical method for the detection and identification of mixtures of sulfonylurea (SU) herbicides in aqueous samples. Because of increased usage, persistent behavior, and potential for crop damage, an environmental method of analysis capable of evaluating SU herbicides in a swift and effective manner is necessary. Eight SU herbicides were evaluated using ESI–AP-IMS quadrupole mass spectrometry. The selected herbicides were chosen based upon availability and scope of use. The SU herbicide species were qualitatively identified using quadrupole mass spectrometry, followed by the determination of reduced mobility values for characteristic ions. Various mixtures of rimsulfuron, metsulfuron-methyl, prosulfuron, sulfometuron-methyl, tribenuron-methyl, and primisulfuron-methyl could be revealed using AP-IMS. The ease of use, ability to operate under ambient conditions, and relatively rapid data acquisition times make ESI–AP-IMS an attractive candidate for the analysis of aqueous environmental field samples. © 2002 Wiley Periodicals, Inc. Field Analyt Chem Technol 5: 302–312, 2001; DOI 10.1002/fact.10010
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Development and evaluation of a low thermal mass gas chromatograph for rapid forensic GC–MS analyses Field detection and identification of a bioaerosol suite by pyrolysis-gas chromatography-ion mobility spectrometry* Multivariate data analysis of fluorescence signals from biological aerosols Biological agent detection and identification by the Block II Chemical Biological Mass Spectrometer Rapid determination of bacteria in drinking water using an ATP assay
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1