{"title":"油棕纤维聚合物复合板的制备:杂化阻燃配方对热机械性能的影响","authors":"Suoware To, Edelugo So","doi":"10.4172/2169-0022.1000472","DOIUrl":null,"url":null,"abstract":"Various oil palm fibre reinforced polyester composite (OPFPC) panels has been fabricated with different FR formulations at increasing percentage loading using hand lay-up compression moulding technique. The effects of aluminium hydroxide (ATH), ammonium polyphosphate (APP), their hybridization and synergism with carbon black (CB) on the mechanical and thermal properties have been investigated. The results obtained showed that 12% ATH inclusion in the OPFC enhanced the tensile strength (TS), tensile modulus (TM) and flexural strength (FS) relative to 0%OPFC panel by 16.2%, 5.9% and 71.2%, respectively. The inclusion of 15%APP-GAP/CB decreased in TS and FS by 18.8% and 20.8% respectively while 18%ATH/APP-GAP/CB hybrid formulation decreased the most by 28.1% in TM showing poor performance in the presence of CB. TGA results reveals that the inclusion of 12%ATH and 15%APP-GAP/CB improved the thermal degradation relative to the 0%OPFC by 5.1°C and 20.48°C respectively while other FR formulations exhibited a decrease. Char residue at 900°C which signifies the end of the test increased significantly for all the FR formulations with 15%APP-GAP/CB observed as the highest at 17.47% and 12%APP-GAP as the least at 10.53%. The inclusion of 12%ATH in the OPFC panel suggest a better mechanical and thermal stability while the inclusion of 15%APP-GAP/CB suggest a better flame retardancy owing to the highest char formation.","PeriodicalId":16326,"journal":{"name":"Journal of Material Sciences & Engineering","volume":"43 1","pages":"1-6"},"PeriodicalIF":0.0000,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Fabrication of Oil Palm Fibre Polymer Composite Panel: Impact of Hybridized Flame Retardant Formulations on Thermo-Mechanical Properties\",\"authors\":\"Suoware To, Edelugo So\",\"doi\":\"10.4172/2169-0022.1000472\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Various oil palm fibre reinforced polyester composite (OPFPC) panels has been fabricated with different FR formulations at increasing percentage loading using hand lay-up compression moulding technique. The effects of aluminium hydroxide (ATH), ammonium polyphosphate (APP), their hybridization and synergism with carbon black (CB) on the mechanical and thermal properties have been investigated. The results obtained showed that 12% ATH inclusion in the OPFC enhanced the tensile strength (TS), tensile modulus (TM) and flexural strength (FS) relative to 0%OPFC panel by 16.2%, 5.9% and 71.2%, respectively. The inclusion of 15%APP-GAP/CB decreased in TS and FS by 18.8% and 20.8% respectively while 18%ATH/APP-GAP/CB hybrid formulation decreased the most by 28.1% in TM showing poor performance in the presence of CB. TGA results reveals that the inclusion of 12%ATH and 15%APP-GAP/CB improved the thermal degradation relative to the 0%OPFC by 5.1°C and 20.48°C respectively while other FR formulations exhibited a decrease. Char residue at 900°C which signifies the end of the test increased significantly for all the FR formulations with 15%APP-GAP/CB observed as the highest at 17.47% and 12%APP-GAP as the least at 10.53%. The inclusion of 12%ATH in the OPFC panel suggest a better mechanical and thermal stability while the inclusion of 15%APP-GAP/CB suggest a better flame retardancy owing to the highest char formation.\",\"PeriodicalId\":16326,\"journal\":{\"name\":\"Journal of Material Sciences & Engineering\",\"volume\":\"43 1\",\"pages\":\"1-6\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2018-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Material Sciences & Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4172/2169-0022.1000472\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Material Sciences & Engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4172/2169-0022.1000472","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
摘要
各种油棕纤维增强聚酯复合材料(OPFPC)板已制造不同的FR配方在增加百分比的负载使用手工铺层压缩成型技术。研究了氢氧化铝(ATH)、聚磷酸铵(APP)及其与炭黑(CB)的杂化和增效作用对复合材料力学性能和热性能的影响。结果表明,与0%OPFC相比,12% ATH包埋OPFC的拉伸强度(TS)、拉伸模量(TM)和抗弯强度(FS)分别提高了16.2%、5.9%和71.2%。15%APP-GAP/CB在TS和FS中分别下降18.8%和20.8%,而18%ATH/APP-GAP/CB混合配方在TM中下降最多,下降28.1%,表明在CB存在下表现不佳。TGA结果表明,相对于0%的opfc,加入12%的ath和15%的app - gap /CB的热降解率分别提高了5.1℃和20.48℃,而其他FR配方的热降解率则有所下降。在900°C时,所有FR配方的焦渣残留量显著增加,其中15%APP-GAP/CB最高,为17.47%,12%APP-GAP最低,为10.53%。在OPFC面板中包含12%的ath表明有更好的机械和热稳定性,而包含15%的app - gap /CB由于最高的炭形成而表明有更好的阻燃性。
Fabrication of Oil Palm Fibre Polymer Composite Panel: Impact of Hybridized Flame Retardant Formulations on Thermo-Mechanical Properties
Various oil palm fibre reinforced polyester composite (OPFPC) panels has been fabricated with different FR formulations at increasing percentage loading using hand lay-up compression moulding technique. The effects of aluminium hydroxide (ATH), ammonium polyphosphate (APP), their hybridization and synergism with carbon black (CB) on the mechanical and thermal properties have been investigated. The results obtained showed that 12% ATH inclusion in the OPFC enhanced the tensile strength (TS), tensile modulus (TM) and flexural strength (FS) relative to 0%OPFC panel by 16.2%, 5.9% and 71.2%, respectively. The inclusion of 15%APP-GAP/CB decreased in TS and FS by 18.8% and 20.8% respectively while 18%ATH/APP-GAP/CB hybrid formulation decreased the most by 28.1% in TM showing poor performance in the presence of CB. TGA results reveals that the inclusion of 12%ATH and 15%APP-GAP/CB improved the thermal degradation relative to the 0%OPFC by 5.1°C and 20.48°C respectively while other FR formulations exhibited a decrease. Char residue at 900°C which signifies the end of the test increased significantly for all the FR formulations with 15%APP-GAP/CB observed as the highest at 17.47% and 12%APP-GAP as the least at 10.53%. The inclusion of 12%ATH in the OPFC panel suggest a better mechanical and thermal stability while the inclusion of 15%APP-GAP/CB suggest a better flame retardancy owing to the highest char formation.