二维锡氧化物的润湿和光催化行为

Sunny Kumar, S. Suresh
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摘要

在各种二维氧化物中,半导体锡氧化物因其在催化剂、能量收集、水净化、电子设备和空间应用方面的前景而特别有趣。本研究采用三种合成方法,探讨了锡板氧化物的性质及其应用。通过扫描电子能谱、紫外光谱、X射线衍射、红外光谱和光致发光等技术对其进行了表征。SEM图像显示了氧化锡材料的形貌。元素分析锡和氧的含量分别为~ 55%和44%。FTIR光谱证实了Sn-O从振动峰的功能。X射线衍射图显示有明显的衍射峰,表明氧化锡结晶度的形成。用亚甲基蓝测试了氧化锡样品的光吸收活性,以探索氧化锡表面特征如何吸收染料的完整性。孔隙度和表面变化导致光活性增加。氧化锡片在紫外光下发出绿色荧光,其发射可能取决于层数和浓度。实验观察了69°氧化锡片上水滴接触角的测量。本文还研究了基于分子动力学理论的接触角测量方法对单层氧化亚锡的影响。基于以上结果,该材料可作为光催化剂、药物传递和太阳能电池薄膜应用。
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Wetting and Photocatalytic Behavior of Two-Dimensional Tin Oxides
Among the variety of two-dimensional oxides, tin oxides semiconducting are particularly interesting because of their promising in catalyst, energy harvesting, water purification, electronics device and space applications. In this study, three synthesized methods use adopted to explore the properties and application of oxides of tin sheets. The methods are air oxidation, aqueous and non-aqueous which characterized through techniques such as SEM-EDS, UV -spectroscopy, X ray diffraction, FTIR and photoluminescence. From SEM image showed the morphology of the tin oxide materials. The percentage of tin and oxygen from elemental analysis was ~ 55 % and 44 % respectively. FTIR spectra confirmed that Sn-O functional from the vibration peak. The X- ray diffraction pattern shows that prominent diffraction peak which indicates formation of tin oxide crystallinity. A photoabsorbtiy activity was tested in the tin oxide sample with methylene blue to explore how the tin oxide surface featured absorbs the integrity of a dye. Porosity and a surface alteration resulted in a increase in photoactivity. The tin oxide sheets emit green fluorescence in the UV light and emission might be dependent on the number of layers and concentration of it. The water droplet contact angle measure on the tin oxide sheets which is experimentally observed 69°. The theoretically molecular dynamics-based contact angle measurement was also studied on monolayer of stannous oxide, stannic oxide with effect of substrate. Based on above results, this material can be utilized as a photo-catalyst, drug delivery and thin film application of solar cell.
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