SnO2衬底在分光型太阳能电池顶电池中的应用

Sinae Kim, S. Kasashima, P. Sichanugrist, M. Konagai
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摘要

我们开发了一种光谱分裂型太阳能电池,分别使用a- si和CIGS作为顶部和底部电池。为了提高其性能,必须开发具有高Voc和短波长的良好响应的顶部a-Si电池。到目前为止,ZnO一直被用作前端TCO。但是,由于ZnO的带隙比SnO2的带隙小,所以用SnO2代替ZnO更好。此外,在这种分裂太阳能电池中,不需要前部TCO有太多的纹理。在这里,我们初步介绍了如何将商业和朦胧的二氧化锡应用于顶电池。为了使SnO2表面平整,采用了氩处理。结果表明,SnO2表面光滑,Voc高达0.967V。
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Application of SnO2 substrate to top cell for spectrum splitting type solar cell
We have developed a spectrum splitting type solar cell using a-Si and CIGS as the top and bottom cells, respectively. To increase its performance the top a-Si cell with high Voc and good response at the short wavelength has to be developed. Up to now ZnO has been used as the front TCO. However, since the band gap of ZnO is lower than the one of SnO2, it is better to use SnO2 instead of ZnO. Furthermore, in this splitting solar cell there is no need for front TCO to be much textured. Here we present a initial introduction how to apply commercial and hazy SnO2 to the top cell. Ar treatment has been used in order to flatten the surface of SnO2. As the results high Voc as high as 0.967V has been achieved with smoother SnO2 surface.
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