双层钙钛矿太阳能电池的设计与器件建模研究

Madhu Allalla, N. Shukla, Sweta Minj, S. Tiwari
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摘要

近年来,有机-无机钙钛矿基太阳能电池以其独特的性能成为光伏领域的一场革命。由于铅对光子的吸收强、效率高,因此基于铅钙钛矿层的钙钛矿太阳能电池的研究备受关注。然而,这些装置的毒性、稳定性和生态挑战因素是商业化生产进展的主要挑战。在这方面,研究和数值模拟钙钛矿太阳能电池使用替代候选人是锡作为钙钛矿材料进行了。由于钙钛矿太阳能电池具有与铅-钙钛矿太阳能电池相似的光伏性能,因此为了克服钙钛矿太阳能电池的毒性、稳定性和生态挑战影响,稍后将对其进行研究。因此,研究了单吸收剂和双吸收剂CH3NH3SnI3和CH3NH3SnBr3以及无空穴传输层对提高钙钛矿器件转换效率的影响。模拟结果表明,与其他HTL材料相比,基于无HTL和双吸收层的钙钛矿太阳能电池的功率转换效率提高了21.3%。因此,在钙钛矿太阳能电池设计中加入双吸收层可能被认为是未来锡钙钛矿太阳能电池的新设计。采用1DSolar Cell电容模拟器(1D- SCAPS)进行了数值模拟。
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Study of Design and Device Modeling of Double layered Perovskite Solar Cells
Recently, organic-inorganic perovskite-based solar cells have become a revolution in photovoltaic field due to their unique properties. Several studies were focused on perovskite solar cells based on Pb perovskite layer as lead provides strong absorption of photons and have high efficiency. However, the factor of toxicity, stability and ecological challenges of these devices is the main challenge to the progress in commercial production. In this, study and numerical modeling of perovskite solar cells using an alternative candidate which is tin as a perovskite material has been carried out. This later is investigated in order to overcome the toxicity, stability and ecological challenges effects on perovskite solar cells, as they exhibit similar photovoltaic performances as Pb-perovskite solar cells. Therefore, the effect of single and double absorbent i.e. CH3NH3SnI3 and CH3NH3SnBr3 and no Hole Transport Layer is studied and investigated to enhance the conversion efficiency of perovskite devices. The obtained simulation results illustrate that perovskite solar cells based on no HTL and double absorbent layer exhibit 21.3% of power conversion efficiency compared to that with other HTL materials. Thus, adding double absorbent layer in perovskite solar cell design possibly will be considered as novel designing for future Sn-perovskite solar cells. The numerical simulation was performed using 1DSolar Cell Capacitance Simulator (1D- SCAPS).
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