应用伯克利热堆肥法从食物垃圾中提取堆肥的化学和光谱特性

Bruna Oliveira, M. A. Leal, Danielle França de Oliveira, A. García
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引用次数: 0

摘要

本研究旨在通过13C核磁共振CP/MAS技术,结合化学计量学、物理和化学参数的评价,对采用热堆肥伯克利法(HCBM)的食物垃圾在低投入条件下堆肥30天产生的堆肥进行表征。方法采用热堆肥伯克利法对餐厨垃圾进行堆肥处理。在第7、9、11、13、15、17、19、21、23和25天进行轮作,共11次轮作,量化温度、pH、电导率、干密度、潜在CO2排放和潜在NH3排放。25 d后测定堆肥中的金属含量。通过13C-NMR CP - MAS光谱和化学计量学分析监测堆肥过程的结构变化。结果堆肥立即进行并持续15天,转化为更不稳定的脂质、碳水化合物和蛋白质分子(CAlkyl-H,R;CAlkyl-O;15天后,CO2和NH3的排放量减少,同时保留了具有更多芳香和非极性特征的顽固性分子(caromtic - h,R;CAromatic-O, N)。结论施用HCBM堆肥25 d后获得的堆肥具有较好的疏水性和芳香性,且含有丰富的植物营养重要矿质元素。将HCBM应用于食物垃圾,可以在生态生产条件下获得稳定的堆肥。
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Chemical and spectroscopy characterization of a compost from food waste applying the hot composting Berkeley method
Purpose This study aims to characterize the compost produced under low input conditions in thirty days of composting from food wastes applying the hot composting Berkeley method (HCBM) by 13C NMR CP/MAS techniques combined with evaluation of chemometric, physical and chemical parameters. Method The composting process from food waste was carried out following the recommendations of the Hot Composting Berkeley method. At 7, 9, 11, 13, 15, 17, 19, 21, 23 and 25 days turning was carried out, totaling eleven turns and the temperature, pH, electrical conductivity, dry density, potential CO2 emission and potential NH3 emission were quantified. The metal content in the compost was determined after 25 days. The structural modifications of compost process were monitored by 13C-NMR CP MAS spectroscopic and chemometrics analysis. Results Composting takes place immediately and continues for 15 days through transformation to more labile lipid, carbohydrate and proteinaceous molecules (CAlkyl-H,R; CAlkyl-O; CAlkyl-O,N) with increasing temperature and pH. After 15 days, there is a CO2 and NH3 emission reduction as well as preservation of recalcitrant molecules with more aromatic and nonpolar characteristics (CAromatic-H,R; CAromatic-O,N). Conclusion The compost obtained at 25 days of composting by applying HCBM has greater hydrophobicity and aromaticity and is rich in mineral elements important for plant nutrition. The application of HCBM to food waste allowed to obtain a stabilized compost in ecological production conditions.
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来源期刊
CiteScore
2.10
自引率
26.70%
发文量
0
审稿时长
13 weeks
期刊介绍: The International Journal of Recycling of Organic Waste in Agriculture is an open access journal that publishes high-quality solicited and unsolicited articles, in all areas of Recycling of organic waste including: -Solid waste reuse in agriculture -Waste water reuse in agriculture -Utilization of organic wastes: composting -Ways to reduce, reuse and recycle organic waste -Social and economic impact of reduction, reuse and recycling of organic waste in agriculture -Methods to raise the public awareness of recycling and reuse of organic waste in agriculture -Organic waste utilization in animal and poultry nutrition -Urban food waste composting
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