异戊烷+二氧化碳和异戊烷+甲烷的笼形物水合物:解离条件的实验测量

A. Mohammadi, D. Richon
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引用次数: 14

摘要

本文报道了异戊烷+二氧化碳和异戊烷+甲烷笼形水合物在(273.5 ~ 282.4)K和(275.5 ~ 285.7)K温度范围内的离解实验数据。实验数据采用等时压力搜索法生成。通过生成新的异戊烷+甲烷笼形水合物的解离数据,并将其与文献报道的实验数据进行比较,验证了该方法的可靠性。可接受的一致性证明了本工作中使用的实验方法的可靠性。最后将所有被测体系的实验数据与文献报道中不含异戊烷的相应实验数据进行比较,以确定其促进作用。
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Clathrate Hydrates of Isopentane + Carbon Dioxide and Isopentane + Methane: Experimental Measurements of Dissociation Conditions
In this work, experimental dissociation data for clathrate hydrates of isopentane + carbon dioxide and isopentane + methane are reported in the temperature ranges of (273.5-282.4) and (275.5-285.7) K, respectively. The experimental data were generated using an isochoric pressure-search method. The reliability of this method is examined by generating new dissociation data for clathrate hydrates of isopentane + methane and comparing them with the experimental data reported in the literature. The acceptable agreement demonstrates the reliability of the experimental method used in this work. The experimental data for all measured systems are finally compared with the corresponding experimental data in the absence of isopentane reported in the literature to identify its promotion effects.
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