{"title":"红外光谱和SERS光谱研究冷沉积铜催化反应的比较","authors":"M. Lust, A. Otto, A. Pucci","doi":"10.1109/ICIMW.2004.1422144","DOIUrl":null,"url":null,"abstract":"Infrared (IR) and surface-enhanced Raman spectroscopy (SERS) of similarly prepared samples show different results that cannot be explained by different selection rules. One main difference is the missing of a signal of NO in the SERS spectra, only reaction products like N/sub 2/ and N/sub 2/O could be seen, whereas in IR clearly NO vibrations were detected. IR spectra were taken to investigate the influence of additional heat and additional photons during the measurement. Besides desorption, no influence like increase of the reaction products N/sub 2/ or N/sub 2/O could be found. It seems to us that a disturbance of the investigated system due to laser irradiation during SERS is not the explanation for the different findings.","PeriodicalId":13627,"journal":{"name":"Infrared and Millimeter Waves, Conference Digest of the 2004 Joint 29th International Conference on 2004 and 12th International Conference on Terahertz Electronics, 2004.","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2004-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Comparison of IR and SERS spectroscopy for investigation of catalytic reactions on cold-deposited Cu\",\"authors\":\"M. Lust, A. Otto, A. Pucci\",\"doi\":\"10.1109/ICIMW.2004.1422144\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Infrared (IR) and surface-enhanced Raman spectroscopy (SERS) of similarly prepared samples show different results that cannot be explained by different selection rules. One main difference is the missing of a signal of NO in the SERS spectra, only reaction products like N/sub 2/ and N/sub 2/O could be seen, whereas in IR clearly NO vibrations were detected. IR spectra were taken to investigate the influence of additional heat and additional photons during the measurement. Besides desorption, no influence like increase of the reaction products N/sub 2/ or N/sub 2/O could be found. It seems to us that a disturbance of the investigated system due to laser irradiation during SERS is not the explanation for the different findings.\",\"PeriodicalId\":13627,\"journal\":{\"name\":\"Infrared and Millimeter Waves, Conference Digest of the 2004 Joint 29th International Conference on 2004 and 12th International Conference on Terahertz Electronics, 2004.\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2004-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Infrared and Millimeter Waves, Conference Digest of the 2004 Joint 29th International Conference on 2004 and 12th International Conference on Terahertz Electronics, 2004.\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/ICIMW.2004.1422144\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Infrared and Millimeter Waves, Conference Digest of the 2004 Joint 29th International Conference on 2004 and 12th International Conference on Terahertz Electronics, 2004.","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/ICIMW.2004.1422144","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Comparison of IR and SERS spectroscopy for investigation of catalytic reactions on cold-deposited Cu
Infrared (IR) and surface-enhanced Raman spectroscopy (SERS) of similarly prepared samples show different results that cannot be explained by different selection rules. One main difference is the missing of a signal of NO in the SERS spectra, only reaction products like N/sub 2/ and N/sub 2/O could be seen, whereas in IR clearly NO vibrations were detected. IR spectra were taken to investigate the influence of additional heat and additional photons during the measurement. Besides desorption, no influence like increase of the reaction products N/sub 2/ or N/sub 2/O could be found. It seems to us that a disturbance of the investigated system due to laser irradiation during SERS is not the explanation for the different findings.
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