喀麦隆比塔雷-奥亚手工金矿区尾矿土环境地球化学研究

V. Manga, Gladys Nchang Neba, Emmanuel Cheo Suh
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引用次数: 24

摘要

对喀麦隆东部Betare-Oya金矿区干尾矿和湿尾矿中微量元素浓度的变化进行了研究。采用ICP-MS对41份表层沉积物样品进行重金属分析,并采用富集比和地质累积指数(Igeo)对污染进行评价;使用来自偏远地区的样本作为对照。尾矿中除Sr和Nb外,其余微量元素均较背景(对照)值显著增加。认为异位沉积可能是锶分布的主要原因。亲石元素之间有很强的相关性;Y, Nb, Ce, La和Pb。它们之间的关联性也很强,即Nb/Ce(.73)和La/Ce(.63)。这些元素在样品中的密切联系可能表明来自长英质岩石(主要是花岗岩和片麻岩)的抗性重矿物的影响。Cu、Zn、Sr和Ba的分布与含硫化物矿物的矿化作用和云母片岩风化形成粘土有关。Cu、Zn、As、W、Mo和Ag已被确定为潜在污染物。与荷兰土壤质量准则相比,这些元素高于目标值,低于干预水平。就其效力而言,砷被认为是最具威胁性的元素。砷在这一地区的分布似乎受到采矿活动的控制。
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Environmental Geochemistry of Mine Tailings Soils in the Artisanal Gold Mining District of Betare -Oya, Cameroon
Changes in trace element concentrations in mine tailings (dry and wet) were investigated in the gold mining area of Betare-Oya, Eastern Cameroon. Forty-one surface sediment samples were analyzed using ICP-MS for heavy metals and pollution was assessed using Enrichment Ratio and Geo Accumulation Index (Igeo); using a sample from a remote area as control.Trace elements in mine tailings show significant increase compared to the background (control) values, with the exception of Sr and Nb. It is suggested that allochtonous deposition may account for Sr distribution. A strong correlation is observed between the lithophile elements; Y, Nb, Ce, La, and Pb. Their association with each other is also strong, i.e. Nb/Ce (.73) and La/Ce (.63). The close association of these elements in the samples may be an indication of the effect of resistant heavy minerals from felsic rocks (mainly granites and gneisses). Cu, Zn, Sr and Ba distribution is associated with mineralisation of sulphide-bearing minerals and clay formation from weathering of mica schist. Cu, Zn, As, W, Mo and Ag have been identified as potential pollutants. Compared to the Dutch soil quality guidelines, these elements are above the target values and below the intervention levels. Arsenic is considered to be the most threatening element, with regards to its potency. The distribution of As in this area appears to be controlled by mining activities.
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