离子液体萃取净化石油馏分

H. D. Huseynov
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摘要

萃取提纯工艺目前正在深入研究,作为石油馏分提纯的一种替代方法,具有广阔的前景。问题的关键是,随着技术的发展和燃料和油品消费的增加,对其质量特性的要求越来越高。同时,特别注意其组成中芳烃、含硫化合物和树脂化合物的含量。本文综述了用传统溶剂和“绿色”溶剂离子液体作为萃取剂对各种油分进行萃取纯化的研究结果,说明了离子液体萃取纯化的有效性。本文还介绍了离子液体萃取与氧化提纯相结合的工艺研究。文章中列出了阿塞拜疆国家科学院石化工艺研究所对各种用途的石油馏分,特别是变压器油馏分、催化裂化和重整汽油、AMG-10液压油、Naftalan油、柴油以及不同粘度值的石油馏分进行的离子液体萃取提纯研究的结果。并证实了不同正阴离子组合的离子液体(甲酸乙酯、苯胺酸酯、n -甲基吡啶酮乙酸酯等)作为选择性溶剂,有可能得到石油产品。
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IONIC LIQUID EXTRACTION CLEANING OF PETROLEUM FRACTIONS
The extraction purification process is currently being intensively studied and has a great future as an alternative method of purification of petroleum fractions. The point is that the development of technology and rise in the consumption of fuels and oils calls for tightening of requirements to their quality characteristics. At the same time, special attention is paid to the content of aromatic hydrocarbons, sulfur-containing and resinous compounds in their composition. The present review considers the results of studies of extractive purification of various oil fractions using both traditional and "green" solvents - ionic liquids as an extractant providing for the effectiveness of ion-liquid extraction purification. The article also describes studies on combining the process of ion-liquid extraction with an oxidative purification method. The results of studies carried out at the Institute of Petrochemical Processes of the National Academy of Sciences of Azerbaijan on ion-liquid extraction purification of petroleum distillates for various purposes, in particular, transformer oil distillate, catalytic cracking and reforming gasoline, AMG-10 hydraulic fluid, Naftalan oil, diesel fuel, as well as oil distillates fractions with different viscosity values, are shown in the article. Also, the possibility getting petroleum products when used as a selective solvent of ionic liquids (morpholformate, anilinformate, N-methylpyrrolidone acetate, etc.) differing in cationic-anionic combination is substantiated.
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