a-Si:H/μc-Si:H异质结p-i-n太阳能电池性能的优化研究

Md Nazmul Islam, H. R. Ghosh
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摘要

本文通过改变太阳能电池的设计参数,如-层厚度、带隙、供体和受体浓度等,找到了氢化非晶硅(a- si:H)和氢化微晶硅(μc-Si:H)异质结p-i-n太阳能电池的最佳结构。A - si:H薄层厚度为1 ~ 5 nm,然后是厚度为1400 ~ 1600 nm的A - si:H薄层,然后是厚度为1 ~ 5 nm的n薄层,受体浓度为102 cm−3,施主浓度为1020 cm−3,p-、i-和n-层的带隙较高,A - si:H薄层的带隙接近2.2 eV, A - si:H薄层的带隙接近1.85 eV, μc-Si:H薄层的带隙接近1.2 eV,表现出较好的性能。优化后的电池JSC为18.93 mA/cm2, VOC为1095 mV,填充系数为0.7124,效率为14.77%。在300-650 nm波长范围内,数值设计的电池的整体外量子效率也保持在85- 95%之间。这表明该器件在高频和低频(即紫外线、近可见光和可见光波长)下都能发挥最佳性能。达卡大学学报:自然科学版,69(2):88- 95,2021 (7)
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Performance Enhancement of an a-Si:H/μc-Si:H Heterojunction p-i-n Solar Cell by Tuning the Device Parameters
In this work, the solar cell design parameters like- layer thickness, bandgap, donor and acceptor concentrations are varied to find optimum structure of a hydrogenated amorphous silicon (a-Si:H) and hydrogenated microcrystalline silicon (μc-Si:H) heterojunction p-i-n solar cell. A thin a-Si:H p-layer of 1 to 5 nm followed by a thick a-Si:H i-layer of thickness 1400 to 1600 nm and then thin n-layer of thickness 1 to 5 nm with acceptor concentration of 102 cm−3 and donor concentration of 1020 cm−3 and the bandgaps of p-, i-, and n- layers with higher bandgaps closer to 2.2 eV for a-Si:H p-layer, 1.85 eV for a-Si:H i-layer, and 1.2 eV for μc-Si:H n-layer have showed better performances. The optimum cell has a JSC of 18.93 mA/cm2, VOC of 1095 mV, Fill factor of 0.7124, and efficiency of 14.77%. The overall external quantum efficiency of the numerically designed cell also remained very high from 85-95 % for wavelengths of 300-650 nm range. This indicates that the device will perform its best under both high and low frequency i.e. ultra-violet, near visible and visible light wavelengths. Dhaka Univ. J. Sci. 69(2): 88-95, 2021 (July)
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