在Pt/PtO和PbO2阳极上电化学合成过氧乙酸

Tetiana Andriyivna Bilous, A. Tulskaya, I. Ryshchenko, I. Chahine, V. Bairachnyi
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引用次数: 1

摘要

研究了醋酸水溶液中Pt/PtO和PbO2阳极的阳极反应动力学。硫酸的加入对过氧乙酸的电化学合成有催化作用。证明了过氧化氢颗粒形成促进剂的选择。I, Cl(电流效率为1.2 - 1.5%)颗粒被定义为对铂阳极最有效,I, F(电流效率为0.50 - 0.55%)被定义为对二氧化铅阳极最有效。
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Electrochemical Synthesis of Peroxyacetic Acid on Pt/PtO and PbO2 Anodes
The kinetics of anodic processes on Pt/PtO and PbO2 anodes has been studied in water solutions of acetic acid. The addition of sulfuric acid has a catalytic effect in the electrochemical synthesis of peroxyacetic acid. The choice of promoters of peroxide-particles formation has been proved. I, Cl (current efficiency is 1.2–1.5 %) particles have been defined as the most effective for platinum anode and I, F (current efficiency is 0.50–0.55 %) have been defined as the most effective for lead-dioxide anode.
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