以离子液体为结构的聚苯胺-原子金修饰铂电极增强电化学传感

Parthojit Chakraborty, Hiroki Kawakami, Anifatul Faricha, T. Chang, M. Sone, T. Nakamoto
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引用次数: 2

摘要

当前的传感器阵列需要多个具有部分选择性的传感膜。然而,制备多个传感膜是很麻烦的。新型传感材料,如掺杂原子金的聚苯胺,由于其“可调谐”的电催化活性,是传感膜的首选候选材料。本文研究了一种以双原子金电催化剂和离子液体为电解质装饰聚苯胺-铂电极的传感器结构。证实了改性纳米复合材料对醇电氧化的电催化活性。为了实时应用,建议在离子液体电解质中选择合适的参比电极。
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Polyaniline-atomic Au modified platinum electrode with ionic liquid as configuration for enhanced electrochemical sensing
Current sensor arrays require multiple sensing films with partial selectivities. However, preparation of multiple number of sensing films is cumbersome. Novel sensing materials such as polyaniline doped with atomic gold are favoured candidates for sensing films due to "tunable" electrocatalytic activity. This paper explores a sensor configuration of polyaniline-platinum electrodes decorated with bi-atomic gold electrocatalyst and ionic liquid as electrolyte. Electrocatalytic activity of the modified nanocomposite towards electrooxidation of alcohols is confirmed. For real-time application, suitable choice of reference electrode operational in ionic liquid electrolyte is suggested.
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