双螺杆挤出机热机械处理回收废橡胶

A. Hejna, Ł. Zedler, P. Kosmela, A. Olszewski, Paulina Burger, K. Formela
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引用次数: 8

摘要

废旧轮胎的回收利用是一个重大的环境和经济问题。主要的回收途径之一是粉碎轮胎,从而产生地面轮胎橡胶。这种材料可以很容易地作为填料引入到各种聚合物基体中,从而减少了传统石油基材料的使用。在这种情况下,必须确保足够的界面相容性,这可以通过对橡胶表面进行适当的改性来实现。不同的轮胎表面处理旨在激活其表面并引入官能团,为界面相互作用和大量回收材料的结合提供可能性。因此,在本文中,我们研究了双螺杆挤出机中热处理对轮胎橡胶外观和化学结构的影响。此外,对于每组工艺参数,计算了加工所需的具体机械能,为分析过程的潜在工业应用提供了必要的见解。在“绿色”工艺和材料的发展过程中,能源需求应被视为一个非常重要的问题。
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Recycling of Waste Rubber by Thermo-Mechanical Treatment in a Twin-Screw Extruder
The recycling of waste tires is a significant environmental and economic issue. One of the leading recycling routes is the shredding of tires, resulting in the generation of ground tire rubber. This material can be easily introduced into various polymer matrices as a filler, reducing the use of conventionally applied petroleum-based materials. In such cases, it is essential to ensure sufficient interfacial compatibility, which can be achieved by the proper modification of the rubber surface. Different treatments of ground tire rubber aim to activate its surface and introduce functional groups, providing the possibility for interfacial interactions and the incorporation of significant amounts of recycled material. Therefore, in the presented paper, we examined the impact of thermo-mechanical treatment in a twin-screw extruder on the appearance and chemical structure of ground tire rubber. Moreover, for each set of process parameters, the specific mechanical energy required for processing was calculated, providing essential insights for the potential industrial application of the analyzed process. The energy demand should be considered as a very important issue during the development of “greener” processes and materials.
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