一种新型铜-酞菁核丙烯酸酯嵌段共聚物的合成、表征及自组装性能

R. Saha, B. Mandal
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引用次数: 0

摘要

采用原子转移自由基聚合的多步反应方案合成了一种新型的以铜-酞菁(CuPc)为核心的二嵌段丙烯酸酯共聚物。该材料具有两亲性,由一个CuPc核心和八个共聚物臂组成。通过紫外可见光谱(UV-Vis)、红外光谱(FT-IR)、核磁共振氢谱(1H-NMR)和元素分析对该新型两亲性材料及其中间体进行了表征。通过光学、原子力和扫描电镜对该材料的自组装特性进行了初步研究。
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Synthesis, Characterization and Self-Assembly Properties of a New Copper-Phthalocyanine Core Acrylate Block Copolymer
A new di-block acrylate copolymer with a Copper-Phthalocyanine (CuPc) core has been synthesized via a multi-step reaction scheme involving the atom-transfer radical polymerization. This material displayed amphiphilic character and consists of a CuPc core with eight copolymer arms. This new amphiphilic material and related intermediates have been characterized by UV-Vis, FT-IR, 1H-NMR and elemental analysis. A preliminary study involving self-assembly properties of this material by optical, atomic force and scanning electron microscopies is presented.
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