赤铁矿负载双金属催化剂还原地下水中硝酸盐

S. Hamid, Woojin Lee
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引用次数: 8

摘要

本研究考察了2.2% cu -1.6% pd -赤铁矿催化剂在不同硝酸盐浓度、催化剂浓度和循环使用情况下对真实地下水样品的硝酸盐还原效果。结果表明,随着催化剂浓度的增加,硝酸还原效果有所改善。2.2% cu -1.6% pd -赤铁矿对硝酸根的去除率随硝酸根浓度的增加呈线性增加,表明该催化剂具有显著提高的还原能力。采用2.2% cu -1.6% pd -赤铁矿进行5次循环,硝酸盐还原率均在95%以上,氮选择性均在56%左右。研究结果表明,在较宽的初始硝酸盐输入范围内,2.2% cu -1.6% pd -赤铁矿可实现地下水硝酸盐的稳定还原。
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Reduction of nitrate in groundwater by hematite supported bimetallic catalyst
In this study, nitrate reduction of real groundwater sample by 2.2%Cu-1.6%Pd-hematite catalyst was evaluated at different nitrate concentrations, catalyst concentrations, and recycling. Results show that the nitrate reduction is improved by increasing the catalyst concentration. Specific nitrate removal by 2.2%Cu-1.6%Pd-hematite increased linearly with the increase of nitrate concentration showing that the catalyst possesses significantly higher reduction capacity. More than 95% nitrate reduction was observed over five recycles by 2.2%Cu-1.6%Pd-hematite with ~56% nitrogen selectivity in all recycling batches. The results from this study indicate that stable reduction of nitrate in groundwater can be achieved by 2.2%Cu-1.6%Pd-hematite over the wide range of initial nitrate inputs.
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