{"title":"赤铁矿负载双金属催化剂还原地下水中硝酸盐","authors":"S. Hamid, Woojin Lee","doi":"10.12989/AER.2016.5.1.051","DOIUrl":null,"url":null,"abstract":"In this study, nitrate reduction of real groundwater sample by 2.2%Cu-1.6%Pd-hematite catalyst was evaluated at different nitrate concentrations, catalyst concentrations, and recycling. Results show that the nitrate reduction is improved by increasing the catalyst concentration. Specific nitrate removal by 2.2%Cu-1.6%Pd-hematite increased linearly with the increase of nitrate concentration showing that the catalyst possesses significantly higher reduction capacity. More than 95% nitrate reduction was observed over five recycles by 2.2%Cu-1.6%Pd-hematite with ~56% nitrogen selectivity in all recycling batches. The results from this study indicate that stable reduction of nitrate in groundwater can be achieved by 2.2%Cu-1.6%Pd-hematite over the wide range of initial nitrate inputs.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"10 1","pages":"51-59"},"PeriodicalIF":0.0000,"publicationDate":"2016-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":"{\"title\":\"Reduction of nitrate in groundwater by hematite supported bimetallic catalyst\",\"authors\":\"S. Hamid, Woojin Lee\",\"doi\":\"10.12989/AER.2016.5.1.051\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this study, nitrate reduction of real groundwater sample by 2.2%Cu-1.6%Pd-hematite catalyst was evaluated at different nitrate concentrations, catalyst concentrations, and recycling. Results show that the nitrate reduction is improved by increasing the catalyst concentration. Specific nitrate removal by 2.2%Cu-1.6%Pd-hematite increased linearly with the increase of nitrate concentration showing that the catalyst possesses significantly higher reduction capacity. More than 95% nitrate reduction was observed over five recycles by 2.2%Cu-1.6%Pd-hematite with ~56% nitrogen selectivity in all recycling batches. The results from this study indicate that stable reduction of nitrate in groundwater can be achieved by 2.2%Cu-1.6%Pd-hematite over the wide range of initial nitrate inputs.\",\"PeriodicalId\":7287,\"journal\":{\"name\":\"Advances in Environmental Research\",\"volume\":\"10 1\",\"pages\":\"51-59\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-03-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"8\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advances in Environmental Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.12989/AER.2016.5.1.051\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advances in Environmental Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.12989/AER.2016.5.1.051","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 8
摘要
本研究考察了2.2% cu -1.6% pd -赤铁矿催化剂在不同硝酸盐浓度、催化剂浓度和循环使用情况下对真实地下水样品的硝酸盐还原效果。结果表明,随着催化剂浓度的增加,硝酸还原效果有所改善。2.2% cu -1.6% pd -赤铁矿对硝酸根的去除率随硝酸根浓度的增加呈线性增加,表明该催化剂具有显著提高的还原能力。采用2.2% cu -1.6% pd -赤铁矿进行5次循环,硝酸盐还原率均在95%以上,氮选择性均在56%左右。研究结果表明,在较宽的初始硝酸盐输入范围内,2.2% cu -1.6% pd -赤铁矿可实现地下水硝酸盐的稳定还原。
Reduction of nitrate in groundwater by hematite supported bimetallic catalyst
In this study, nitrate reduction of real groundwater sample by 2.2%Cu-1.6%Pd-hematite catalyst was evaluated at different nitrate concentrations, catalyst concentrations, and recycling. Results show that the nitrate reduction is improved by increasing the catalyst concentration. Specific nitrate removal by 2.2%Cu-1.6%Pd-hematite increased linearly with the increase of nitrate concentration showing that the catalyst possesses significantly higher reduction capacity. More than 95% nitrate reduction was observed over five recycles by 2.2%Cu-1.6%Pd-hematite with ~56% nitrogen selectivity in all recycling batches. The results from this study indicate that stable reduction of nitrate in groundwater can be achieved by 2.2%Cu-1.6%Pd-hematite over the wide range of initial nitrate inputs.