杂原子包埋环性π扩展反应综述

IF 2.2 4区化学 Q2 CHEMISTRY, ORGANIC Synthesis-Stuttgart Pub Date : 2023-08-17 DOI:10.1055/a-2169-4078

Hideto Ito, Kou P Kawahara, Kenichiro Itami

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引用次数: 1

摘要

杂原子嵌入型多环芳香族化合物(hetero-PACs)是一类有机化合物，在材料科学、化学生物学等诸多研究领域都有重要贡献。在应用中，高效制备异质pacs至关重要。其中，利用合适的含杂原子芳香族化合物(π扩展剂)将未功能化芳香族化合物转化为杂环芳香族化合物是制备杂环芳香族化合物最理想的方法。本文综述了这类杂原子包埋环性π-延伸反应(hetero-APEX)的反应机理和底物范围。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Heteroatom-Embedding Annulative π-Extension (Hetero-APEX) Reactions: An Overview

Heteroatom-embedded polycyclic aromatic compounds (hetero-PACs) are a class of organic compounds contributing to a variety of research fields such as materials science, chemical biology and so on. For applications using hetero-PACs, efficient preparation of hetero-PACs is essential. In particular, reactions transforming unfunctionalized aromatic compounds to hetero-PACs using appropriate heteroatom-containing aromatic compounds (π-extending agents) represent the most ideal way to prepare hetero-PACs. In this review, such heteroatom-embedding annulative π-extension (hetero-APEX) reactions including their reaction mechanisms and scope of substrates are described.

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来源期刊

Synthesis-Stuttgart 化学-有机化学

CiteScore

4.50

自引率

7.70%

发文量

435

审稿时长

1 months

期刊介绍： SYNTHESIS is an international full-paper journal devoted to the advancement of the science of chemical synthesis. It covers all fields of organic chemistry involving synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines. SYNTHESIS provides dependable research results with detailed and reliable experimental procedures and full characterization of all important new products as well as scientific primary data.