二亚硫酸钠在铂电极上的电化学行为及碱溶液中扩散系数的测定

E. Gasana, P. Westbroek, E. Temmerman, H. Thun
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引用次数: 18

摘要

本文研究了二亚硫酸钠在铂电极上的电化学行为。观察到二亚硝酸钠的两个氧化波,形成亚硫酸盐作为稳定的中间物质。人们发现,根据第一波,二亚硫酸钠氧化为亚硫酸盐是由质量输运速率控制的,然而,亚硫酸盐氧化为硫酸盐并不是纯粹由输运现象控制的。利用两个氧化波的极限电流之比,可以通过外推铂电极的小旋转速率来确定二亚硫酸钠的扩散系数。从得到的结果来看,利用第一氧化反应进行分析也是可取的。
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Electrochemical behaviour of sodium dithionite at a platinum electrode and determination of diffusion coefficient in alkaline solution
The electrochemical behaviour of sodium dithionite at a platinum electrode has been investigated in this paper. Two oxidation waves of sodium dithionite were observed with formation of sulfite as a stable intermediate species. It has been found that the oxidation of sodium dithionite to sulfite, according to the first wave, is controlled by the rate of mass transport, the oxidation of sulfite to sulfate, however, is not purely controlled by transport phenomena. Using the ratio of the limiting currents of both oxidation waves it was possible to determine the diffusion coefficient of sodium dithionite by extrapolation to the small rotation rate of the platinum electrode. From the obtained results it is also advisable to make use of the first oxidation reaction for analytical purposes.
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