生物吸附剂(蛋壳、椰枣籽、木瓜籽)对水溶液中亚甲基蓝染料的去除

Mariya Kiran Baloch, R. Brohi, K. M. Brohi, Shafquat Ali Baloch, A. Mahar, M. Kiran
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摘要

由于各种工业出口(如纺织)排放大量有色废水,而没有采用适当的处理方法对这些废水进行脱色,因此水污染受到严重关注。未经处理的液体废水被排放到海洋生态系统,即湖泊、池塘,对水生生物、动植物构成非常严重的威胁。它降低了光渗透到水中深处的能力,导致水体中生物需氧量的减少。因此,有色废水在排放前的处理非常重要。传统的治疗方案既昂贵又耗时。采用经济、环保的吸附剂,可去除纺织染料。考察了蛋壳、枣椰籽、木瓜籽等生物吸附剂对亚甲基蓝染料的去除率及其对投加量mg/g、pH、初始浓度、接触时间和转速rpm等参数的影响。采用傅里叶变换红外光谱、扫描电镜和能量色散光谱对表面吸附剂进行了表征。各种等温线包括拟合的Langmuir Freundlich模型和吸附数据的动力学模型。亚甲基蓝染料在蛋壳、椰枣籽和木瓜籽上的吸附动力学研究遵循伪二级反应。最后用0.1M盐酸对蛋壳、枣椰籽和木瓜籽上的亚甲蓝染料进行解吸。不同吸附剂对染料的还原率不同。吸附材料是一种有益的生态友好型吸附材料。
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THE REMOVAL OF METHYLENE BLUE DYE FROM AQUEOUS SOLUTION THROUGH BIO-ADSORBENTS (EGGSHELL, DATE PALM SEEDS AND PAPAYA SEEDS)
Water pollution is serious concern due to large quantity of colored wastewater discharged from various industrial outlets i.e. textile, and no proper treatment methods are being used to decolor such wastewater. Untreated liquid effluents are discharged in marine ecosystems i.e. lakes, ponds, posing a very serious risk to aquatic life, flora and fauna. It reduces the ability of light penetration to reach deep down in water resulting in a decrement of biological oxygen demand in water bodies. Therefore, the treatment of colored wastewater is significant before discharge. The conventional treatment options are costly and time consuming. The textile dyes can be removed through adsorption using cost effective and eco-friendly adsorbents. This work was aimed to test the potential of Bio-adsorbent waste like eggshells, date palm seeds, and papaya seeds¬¬ to remove methylene blue dye and their effects on following parameters such as dosage mg/g, pH, initial concentration, contact time and speed rpm. The characterization of surface adsorbents was assessed by Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy and Energy Dispersive Spectroscopy. Various isotherms included like fitted Langmuir Freundlich and Kinetic model for the adsorption data. The kinetic study of Methylene blue dye on Adsorbents Eggshell, Date palm seeds and Papaya seeds follow pseudo-second order reaction. Lastly the desorption of Methylene blue dye on Eggshell, Date palm seeds and Papaya seeds using 0.1M HCL. The restoration % of dye on each adsorbent was different found. It can be accepted that adsorbent material as a useful eco–friendly for the removal of MB.
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