首页 > 最新文献

ENVIRONMENTAL CONTAMINANTS REVIEWS最新文献

英文 中文
ENVIRONMENTAL IMPACT ASSESSMENT OF OIL PRODUCING COMMUNITIES IN PART OF THE NIGER DELTA. A CASE STUDY OF IBENO, IKOT ABASI, ONNA AND ESIT-EKET LOCAL GOVERNMENT AREA IN AKWA IBOM STATE, NIGERIA 尼日尔三角洲部分产油社区的环境影响评估。尼日利亚阿夸伊博姆州ibeno、ikot abasi、onna和esit-eket地方政府区域的案例研究
Pub Date : 2022-01-01 DOI: 10.26480/ecr.02.2022.49.56
T. A. Harry, Ekemini John Peter, Nsidibe Akpan Udoduk
An Environmental Impact Assessment was initiated to monitor the distribution and effect of petroleum hydrocarbon pollutants on the quality of the surface water, groundwater, and sediments of Ibeno, Esit-Eket, Onna, and Ikot Abasi. Eighty-one (81) samples were randomly collected from surface water, boreholes, and soil for analyses based on the standard physiochemical parameters for comparison with the World Health Organization (WHO) standard. The variation in the average pH of water was not significant (6.5 to 8.0), well within the range for unpolluted streams. However, the total hydrocarbon content (THC) of the sediments was greater than 200 mg/kg, which is the limit, thus indicating heavy pollution by hydrocarbons. The pollution indices for the potential contaminants were also determined, in which the pollution index of surface water samples and borehole water sample is <1 indicating an unpolluted water body, while the pollution index of sediment samples was > 1, showing polluted sediments.
开展了一项环境影响评价,以监测石油烃污染物对伊贝诺、埃西特-埃基特、Onna和伊科特-阿巴斯地表水、地下水和沉积物质量的分布和影响。从地表水、钻孔和土壤中随机收集81个样本,根据标准理化参数进行分析,并与世界卫生组织(WHO)标准进行比较。水的平均pH值变化不显著(6.5至8.0),完全在未污染溪流的范围内。但沉积物中总烃含量(THC)大于200 mg/kg,为上限,表明烃污染较重。确定了潜在污染物的污染指数,其中地表水样品和钻孔水样的污染指数为1,表明沉积物受到污染。
{"title":"ENVIRONMENTAL IMPACT ASSESSMENT OF OIL PRODUCING COMMUNITIES IN PART OF THE NIGER DELTA. A CASE STUDY OF IBENO, IKOT ABASI, ONNA AND ESIT-EKET LOCAL GOVERNMENT AREA IN AKWA IBOM STATE, NIGERIA","authors":"T. A. Harry, Ekemini John Peter, Nsidibe Akpan Udoduk","doi":"10.26480/ecr.02.2022.49.56","DOIUrl":"https://doi.org/10.26480/ecr.02.2022.49.56","url":null,"abstract":"An Environmental Impact Assessment was initiated to monitor the distribution and effect of petroleum hydrocarbon pollutants on the quality of the surface water, groundwater, and sediments of Ibeno, Esit-Eket, Onna, and Ikot Abasi. Eighty-one (81) samples were randomly collected from surface water, boreholes, and soil for analyses based on the standard physiochemical parameters for comparison with the World Health Organization (WHO) standard. The variation in the average pH of water was not significant (6.5 to 8.0), well within the range for unpolluted streams. However, the total hydrocarbon content (THC) of the sediments was greater than 200 mg/kg, which is the limit, thus indicating heavy pollution by hydrocarbons. The pollution indices for the potential contaminants were also determined, in which the pollution index of surface water samples and borehole water sample is <1 indicating an unpolluted water body, while the pollution index of sediment samples was > 1, showing polluted sediments.","PeriodicalId":11882,"journal":{"name":"ENVIRONMENTAL CONTAMINANTS REVIEWS","volume":"53 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83274451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
THE REMOVAL OF METHYLENE BLUE DYE FROM AQUEOUS SOLUTION THROUGH BIO-ADSORBENTS (EGGSHELL, DATE PALM SEEDS AND PAPAYA SEEDS) 生物吸附剂(蛋壳、椰枣籽、木瓜籽)对水溶液中亚甲基蓝染料的去除
Pub Date : 2022-01-01 DOI: 10.26480/ecr.01.2022.01.08
Mariya Kiran Baloch, R. Brohi, K. M. Brohi, Shafquat Ali Baloch, A. Mahar, M. Kiran
Water pollution is serious concern due to large quantity of colored wastewater discharged from various industrial outlets i.e. textile, and no proper treatment methods are being used to decolor such wastewater. Untreated liquid effluents are discharged in marine ecosystems i.e. lakes, ponds, posing a very serious risk to aquatic life, flora and fauna. It reduces the ability of light penetration to reach deep down in water resulting in a decrement of biological oxygen demand in water bodies. Therefore, the treatment of colored wastewater is significant before discharge. The conventional treatment options are costly and time consuming. The textile dyes can be removed through adsorption using cost effective and eco-friendly adsorbents. This work was aimed to test the potential of Bio-adsorbent waste like eggshells, date palm seeds, and papaya seeds¬¬ to remove methylene blue dye and their effects on following parameters such as dosage mg/g, pH, initial concentration, contact time and speed rpm. The characterization of surface adsorbents was assessed by Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy and Energy Dispersive Spectroscopy. Various isotherms included like fitted Langmuir Freundlich and Kinetic model for the adsorption data. The kinetic study of Methylene blue dye on Adsorbents Eggshell, Date palm seeds and Papaya seeds follow pseudo-second order reaction. Lastly the desorption of Methylene blue dye on Eggshell, Date palm seeds and Papaya seeds using 0.1M HCL. The restoration % of dye on each adsorbent was different found. It can be accepted that adsorbent material as a useful eco–friendly for the removal of MB.
由于各种工业出口(如纺织)排放大量有色废水,而没有采用适当的处理方法对这些废水进行脱色,因此水污染受到严重关注。未经处理的液体废水被排放到海洋生态系统,即湖泊、池塘,对水生生物、动植物构成非常严重的威胁。它降低了光渗透到水中深处的能力,导致水体中生物需氧量的减少。因此,有色废水在排放前的处理非常重要。传统的治疗方案既昂贵又耗时。采用经济、环保的吸附剂,可去除纺织染料。考察了蛋壳、枣椰籽、木瓜籽等生物吸附剂对亚甲基蓝染料的去除率及其对投加量mg/g、pH、初始浓度、接触时间和转速rpm等参数的影响。采用傅里叶变换红外光谱、扫描电镜和能量色散光谱对表面吸附剂进行了表征。各种等温线包括拟合的Langmuir Freundlich模型和吸附数据的动力学模型。亚甲基蓝染料在蛋壳、椰枣籽和木瓜籽上的吸附动力学研究遵循伪二级反应。最后用0.1M盐酸对蛋壳、枣椰籽和木瓜籽上的亚甲蓝染料进行解吸。不同吸附剂对染料的还原率不同。吸附材料是一种有益的生态友好型吸附材料。
{"title":"THE REMOVAL OF METHYLENE BLUE DYE FROM AQUEOUS SOLUTION THROUGH BIO-ADSORBENTS (EGGSHELL, DATE PALM SEEDS AND PAPAYA SEEDS)","authors":"Mariya Kiran Baloch, R. Brohi, K. M. Brohi, Shafquat Ali Baloch, A. Mahar, M. Kiran","doi":"10.26480/ecr.01.2022.01.08","DOIUrl":"https://doi.org/10.26480/ecr.01.2022.01.08","url":null,"abstract":"Water pollution is serious concern due to large quantity of colored wastewater discharged from various industrial outlets i.e. textile, and no proper treatment methods are being used to decolor such wastewater. Untreated liquid effluents are discharged in marine ecosystems i.e. lakes, ponds, posing a very serious risk to aquatic life, flora and fauna. It reduces the ability of light penetration to reach deep down in water resulting in a decrement of biological oxygen demand in water bodies. Therefore, the treatment of colored wastewater is significant before discharge. The conventional treatment options are costly and time consuming. The textile dyes can be removed through adsorption using cost effective and eco-friendly adsorbents. This work was aimed to test the potential of Bio-adsorbent waste like eggshells, date palm seeds, and papaya seeds¬¬ to remove methylene blue dye and their effects on following parameters such as dosage mg/g, pH, initial concentration, contact time and speed rpm. The characterization of surface adsorbents was assessed by Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy and Energy Dispersive Spectroscopy. Various isotherms included like fitted Langmuir Freundlich and Kinetic model for the adsorption data. The kinetic study of Methylene blue dye on Adsorbents Eggshell, Date palm seeds and Papaya seeds follow pseudo-second order reaction. Lastly the desorption of Methylene blue dye on Eggshell, Date palm seeds and Papaya seeds using 0.1M HCL. The restoration % of dye on each adsorbent was different found. It can be accepted that adsorbent material as a useful eco–friendly for the removal of MB.","PeriodicalId":11882,"journal":{"name":"ENVIRONMENTAL CONTAMINANTS REVIEWS","volume":"15 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85571628","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
SPATIAL MODELING OF AIR POLLUTANT CONCENTRATIONS USING GWR AND ANFIS MODELS IN TEHRAN CITY 利用GWR和anfis模型对德黑兰市空气污染物浓度进行空间模拟
Pub Date : 2022-01-01 DOI: 10.26480/ecr.02.2022.78.84
Vahid Isazade, Abdul Baser Qasimi, Keyvan Seraj, Esmail Isazade
Today, air quality is a major subject in city regions that have affected human health, the environment, and the city ecosystem. Therefore, government officials, environmental organizations, health organizations, and city managers often need to model the concentration of air contaminants. This study aimed to compare geographically weighted regression (GWR) modeling and neural network (ANFIS) using Segno and Mamdani rules to spatially predict the concentration density of fNO2, CO, and SO2 pollutant indices. And PM 2.5 for the year 2021 in Tehran. The results of the statistical analysis of Sugeno and Mamdani rules revealed that the (RMSE) in evaluating the ANFIS model with the Mamdani method was 0.895 ppm, and with the Sugno method it was 1.004 ppm, whereas the RMSE in terms of Spatial weighted regression model was obtained on digital model with a height of (12.5 m) and a value of 692.0 ppm. The evaluation results showed that Mamdani and Sugno laws do not have the same and desirable accuracy. For Mamdani law, the RMSE level of PM 2.5 pollutant was (0.71 ppm) and according to Sugno law, this level was obtained for CO pollutant (0.81 ppm). While evaluating the geographically weighted regression model for the four air pollution indices the digital altitude model of (12.5 m) had similar results, which statistically for the digital altitude model of (12.5 m) obtained the RMSE for PM 2.5 (0.82 ppm). The findings of this study demonstrated that the weighted geographic regression model and the ANFI neural network have acceptable functionalities for spatial prediction of air pollutants.
今天,空气质量是影响人类健康、环境和城市生态系统的城市地区的一个主要问题。因此,政府官员、环境组织、卫生组织和城市管理者经常需要模拟空气污染物的浓度。本研究旨在比较基于Segno和Mamdani规则的地理加权回归(GWR)模型和神经网络(ANFIS)模型对fNO2、CO和SO2污染物指数浓度密度的空间预测。还有2021年德黑兰的pm2.5。Sugeno和Mamdani规则的统计分析结果表明,Mamdani方法评价ANFIS模型的RMSE为0.895 ppm, Sugno方法评价ANFIS模型的RMSE为1.004 ppm,而空间加权回归模型评价ANFIS模型的RMSE为692.0 ppm,高度为12.5 m。评价结果表明,Mamdani法和Sugno法的精度不一致。根据Mamdani法,pm2.5污染物的RMSE值为(0.71 ppm),根据Sugno法,CO污染物的RMSE值为(0.81 ppm)。在对四种空气污染指数的地理加权回归模型进行评价时,(12.5 m)数字高度模型的结果与(12.5 m)数字高度模型的结果相似,统计上(12.5 m)数字高度模型获得了PM 2.5的RMSE (0.82 ppm)。研究结果表明,加权地理回归模型和ANFI神经网络对大气污染物的空间预测具有可接受的功能。
{"title":"SPATIAL MODELING OF AIR POLLUTANT CONCENTRATIONS USING GWR AND ANFIS MODELS IN TEHRAN CITY","authors":"Vahid Isazade, Abdul Baser Qasimi, Keyvan Seraj, Esmail Isazade","doi":"10.26480/ecr.02.2022.78.84","DOIUrl":"https://doi.org/10.26480/ecr.02.2022.78.84","url":null,"abstract":"Today, air quality is a major subject in city regions that have affected human health, the environment, and the city ecosystem. Therefore, government officials, environmental organizations, health organizations, and city managers often need to model the concentration of air contaminants. This study aimed to compare geographically weighted regression (GWR) modeling and neural network (ANFIS) using Segno and Mamdani rules to spatially predict the concentration density of fNO2, CO, and SO2 pollutant indices. And PM 2.5 for the year 2021 in Tehran. The results of the statistical analysis of Sugeno and Mamdani rules revealed that the (RMSE) in evaluating the ANFIS model with the Mamdani method was 0.895 ppm, and with the Sugno method it was 1.004 ppm, whereas the RMSE in terms of Spatial weighted regression model was obtained on digital model with a height of (12.5 m) and a value of 692.0 ppm. The evaluation results showed that Mamdani and Sugno laws do not have the same and desirable accuracy. For Mamdani law, the RMSE level of PM 2.5 pollutant was (0.71 ppm) and according to Sugno law, this level was obtained for CO pollutant (0.81 ppm). While evaluating the geographically weighted regression model for the four air pollution indices the digital altitude model of (12.5 m) had similar results, which statistically for the digital altitude model of (12.5 m) obtained the RMSE for PM 2.5 (0.82 ppm). The findings of this study demonstrated that the weighted geographic regression model and the ANFI neural network have acceptable functionalities for spatial prediction of air pollutants.","PeriodicalId":11882,"journal":{"name":"ENVIRONMENTAL CONTAMINANTS REVIEWS","volume":"17 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81276709","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
A REVIEW: EFFECTS OF NITROGENOUS FERTILIZERS ON SOIL (PH, MICROBIAL COMMUNITY, GREENHOUSE GASES EMISSION AND CARBON POOL) 氮肥对土壤(ph、微生物群落、温室气体排放和碳库)的影响
Pub Date : 2022-01-01 DOI: 10.26480/ecr.02.2022.44.48
P. Sharma, A. Tripathi, M. Pandey
With world population increasing at such fast rate and land available to cultivate decreasing substantially, it is of prime need to increase the productivity. This is the reason of increasing use of fertilizer in the world especially N fertilizer because of its direct influence on growth attributes. The main objective of this article is to review the existing literature regarding the effect of nitrogen fertilizer application in soil pH, microbial community, soil carbon pool and emission of Green House Gases. Most researches have shown urea to be the major source of anthropogenic N addition to soil. Studies have concluded that the unmanaged application of N fertilizers in excess amount than what crops utilize is the nerve center favoring pH change. In regards to their impact in microbial community, previous land management practice seemed pivotal. Also, abundance and diversity of greater fraction of microbes (fungi and bacteria) narrowed down with intensified application in cultivated soils in majority of trails studied. Increased efflux of CO2 and N2O was observed in soil fertilized with N however, CH4 emission was limited as methanotrophs were replaced with nitrifiers. Acid rain was highly favored with such emissions. No changes in soil organic carbon pool were seen in short period but in due course of time, decomposition or turnover rate decreased increasing the stability of carbon under lignin rich root residues. Therefore, alterations varying with depth have been noticed in soils treated with N due to mineral association.
随着世界人口的快速增长和可耕地的急剧减少,提高生产力是当务之急。这是世界各国化肥特别是氮肥使用量增加的原因,因为氮肥直接影响到作物的生长特性。本文主要综述了氮肥施用对土壤pH、微生物群落、土壤碳库和温室气体排放的影响。大多数研究表明,尿素是土壤中人为氮添加的主要来源。研究表明,无管理地施用超过作物利用量的氮肥是有利于pH变化的神经中枢。关于它们对微生物群落的影响,以前的土地管理实践似乎至关重要。此外,在大多数试验中,随着施用强度的增加,大部分微生物(真菌和细菌)的丰度和多样性都缩小了。施氮土壤中CO2和N2O的外排增加,但由于甲烷氧化菌被硝化菌取代,CH4的排放受到限制。这种排放物对酸雨非常有利。土壤有机碳库在短时间内没有变化,但随着时间的推移,在富含木质素的根系残余物下,土壤有机碳的分解或周转速率降低,碳的稳定性增加。因此,在施氮处理的土壤中,由于矿物结合,变化随深度而变化。
{"title":"A REVIEW: EFFECTS OF NITROGENOUS FERTILIZERS ON SOIL (PH, MICROBIAL COMMUNITY, GREENHOUSE GASES EMISSION AND CARBON POOL)","authors":"P. Sharma, A. Tripathi, M. Pandey","doi":"10.26480/ecr.02.2022.44.48","DOIUrl":"https://doi.org/10.26480/ecr.02.2022.44.48","url":null,"abstract":"With world population increasing at such fast rate and land available to cultivate decreasing substantially, it is of prime need to increase the productivity. This is the reason of increasing use of fertilizer in the world especially N fertilizer because of its direct influence on growth attributes. The main objective of this article is to review the existing literature regarding the effect of nitrogen fertilizer application in soil pH, microbial community, soil carbon pool and emission of Green House Gases. Most researches have shown urea to be the major source of anthropogenic N addition to soil. Studies have concluded that the unmanaged application of N fertilizers in excess amount than what crops utilize is the nerve center favoring pH change. In regards to their impact in microbial community, previous land management practice seemed pivotal. Also, abundance and diversity of greater fraction of microbes (fungi and bacteria) narrowed down with intensified application in cultivated soils in majority of trails studied. Increased efflux of CO2 and N2O was observed in soil fertilized with N however, CH4 emission was limited as methanotrophs were replaced with nitrifiers. Acid rain was highly favored with such emissions. No changes in soil organic carbon pool were seen in short period but in due course of time, decomposition or turnover rate decreased increasing the stability of carbon under lignin rich root residues. Therefore, alterations varying with depth have been noticed in soils treated with N due to mineral association.","PeriodicalId":11882,"journal":{"name":"ENVIRONMENTAL CONTAMINANTS REVIEWS","volume":"32 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84497365","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ASSESSMENT OF GROUNDWATER QUALITY USING WATER QUALITY INDEX (WQI) METHOD IN SOUTHERN IJAW LOCAL GOVERNMENT AREA OF BAYELSA STATE, NIGERIA 用水质量指数法评价尼日利亚巴耶尔萨州南部伊贾地方政府辖区地下水质量
Pub Date : 2022-01-01 DOI: 10.26480/ecr.02.2022.64.68
Peterside, A.N, Hart, A.I, N. H.O.
This study aims at using Water Quality Index (WQI) method for groundwater assessment in some communities in Southern Ijaw Local Government Area of Bayelsa State, Nigeria. A total of fifteen (15) communities within the LGA were selected and groundwater from hand-dug well (HDW-15 samples) and borehole (BH-15 samples) was sourced during the wet season (July) and dry season (March). The analyses for water quality index was carried out through laboratory APHA standard. The weighted arithmetic water quality method was applied to assess water suitability for drinking purposes. The Quality Index indicated that HDW (67%-good and 33%-poor) and BH (87%-excellent, 13%-very poor) quality during the wet season and HDW (80%- good to excellent, 20%-poor) and BH (100%- good to excellent) during dry season. Spatial variation of water quality index maps for HDW show most deteriorated groundwater quality is centered within hand dug well towards the western part of the area during both wet and dry seasons respectively. Continuous monitoring of the water quality, improvement of environmental quality and sanitation practices is advocated and advised.
本研究旨在利用水质指数(WQI)方法对尼日利亚巴耶尔萨州南伊乔地方政府辖区的一些社区进行地下水评价。在LGA内共选择了15个社区,在雨季(7月)和旱季(3月)从手挖井(HDW-15样本)和钻孔(BH-15样本)中获取地下水。采用实验室APHA标准对水质指标进行了分析。采用加权算术水质法评价饮用水的适宜性。质量指数表明,湿季HDW(67%-好,33%-差)和BH(87%-优,13%-极差)质量,干季HDW(80%-好至优,20%-差)和BH(100%-好至优)质量。从HDW水质指数图的空间变异性来看,干湿季节地下水水质恶化最严重的区域分别集中在西部手挖井内。我们提倡和建议持续监测水质、改善环境质量和卫生措施。
{"title":"ASSESSMENT OF GROUNDWATER QUALITY USING WATER QUALITY INDEX (WQI) METHOD IN SOUTHERN IJAW LOCAL GOVERNMENT AREA OF BAYELSA STATE, NIGERIA","authors":"Peterside, A.N, Hart, A.I, N. H.O.","doi":"10.26480/ecr.02.2022.64.68","DOIUrl":"https://doi.org/10.26480/ecr.02.2022.64.68","url":null,"abstract":"This study aims at using Water Quality Index (WQI) method for groundwater assessment in some communities in Southern Ijaw Local Government Area of Bayelsa State, Nigeria. A total of fifteen (15) communities within the LGA were selected and groundwater from hand-dug well (HDW-15 samples) and borehole (BH-15 samples) was sourced during the wet season (July) and dry season (March). The analyses for water quality index was carried out through laboratory APHA standard. The weighted arithmetic water quality method was applied to assess water suitability for drinking purposes. The Quality Index indicated that HDW (67%-good and 33%-poor) and BH (87%-excellent, 13%-very poor) quality during the wet season and HDW (80%- good to excellent, 20%-poor) and BH (100%- good to excellent) during dry season. Spatial variation of water quality index maps for HDW show most deteriorated groundwater quality is centered within hand dug well towards the western part of the area during both wet and dry seasons respectively. Continuous monitoring of the water quality, improvement of environmental quality and sanitation practices is advocated and advised.","PeriodicalId":11882,"journal":{"name":"ENVIRONMENTAL CONTAMINANTS REVIEWS","volume":"19 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79050403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
POLLUTION EVALUATION AND HEALTH RISK ASSESSMENT OF HEAVY METALS IN STREAM WATER AT EAST AKIM MUNICIPAL ASSEMBLY, GHANA 加纳东阿基姆市议会流水中重金属的污染评价和健康风险评估
Pub Date : 2022-01-01 DOI: 10.26480/ecr.01.2022.15.22
Afua Amponsah Amankwah, Douglas Siaw Baah, E. Acheampong
Water contamination with toxic chemicals such as heavy metals continue to rise globally and particularly in developing countries due to mining, urbanization, and industrialization. In this study, a total of 10 stream water samples were collected from the mining environment. Physicochemical parameters such as pH and heavy metals; arsenic (As), chromium (Cr), nickel (Ni), and lead (Pb) were examined using standard procedures. The study assessed heavy metals concentrations, evaluated the pollution indices, and the health risk (carcinogenic and non-carcinogenic) for the populace (both adult and child) through direct oral intake and dermal contact of stream water in East Akim Municipal Assembly. The results of the concentrations of As (0.114 mg/kg), Cr (0.00000605 mg/kg), Ni (0.025 mg/kg), and Pb (0.257 mg/kg) revealed that they were within acceptable limits prescribed by World Health Organization (WHO) and Water guidelines. Heavy metal evaluation index (HEI) and degree of contamination (Cd) values obtained indicated that all the examined samples were categorized as low (Cd < 1 and HEI < 10). Non-carcinogenic risk indicated that stream water consumption via ingestion and dermal pathways were below the oral reference dose for their respective heavy metals indicating that both age groups may be ingesting safe levels of heavy metals. Furthermore, the non-carcinogenic risk assessment suggest that children are more susceptible to health threats than adults considering both exposure pathways. Also, the hazard quotient and hazard index were < 1 inferring that there is a tolerable degree of non-carcinogenic health risk for both adults and children in the research area. In addition, average values (1.86×10-5 and 7.12×10-5 for adults and children) obtained for the assessment of cancer risk (CR) for CRingestion were within the safe range of 1×10-6 to 1×10-4 while CRdermal contact average values (4.52×10-8 and 2.53×10-7 for adults and children) were above the range recommended by US Environmental Protection Agency. Regardless of the relatively safe indices recorded, precautionary measures are necessary to sustain the aquatic ecosystem and its quality. Efforts must be made to ensure that heavy metals that can pose health risks even in their low concentrations are monitored and kept as low as possible to ensure safety and reduced human health risks.
由于采矿、城市化和工业化,重金属等有毒化学物质的水污染在全球范围内持续上升,特别是在发展中国家。本研究共采集了矿山环境中10个水样。pH、重金属等理化参数;砷(As)、铬(Cr)、镍(Ni)和铅(Pb)采用标准程序进行检测。该研究评估了重金属浓度,评估了污染指数,以及通过直接口服和皮肤接触东阿基姆市议会的水流对民众(成人和儿童)造成的健康风险(致癌和非致癌)。砷(0.114毫克/公斤)、铬(0.00000605毫克/公斤)、镍(0.025毫克/公斤)和铅(0.257毫克/公斤)的浓度结果显示,它们都在世界卫生组织(世卫组织)和水准则规定的可接受限度之内。重金属评价指数(HEI)和污染程度(Cd)值均为低(Cd < 1, HEI < 10)。非致癌风险表明,通过摄入和皮肤途径摄入的溪水中重金属含量低于各自的口服参考剂量,这表明两个年龄组的人可能都摄入了安全水平的重金属。此外,非致癌性风险评估表明,考虑到两种接触途径,儿童比成年人更容易受到健康威胁。危害商数和危害指数均< 1,表明研究区内的成人和儿童存在可耐受程度的非致癌性健康风险。此外,CRingestion致癌风险评估的平均值(成人和儿童分别为1.86×10-5和7.12×10-5)在1×10-6 ~ 1×10-4的安全范围内,而crderskin contact的平均值(成人和儿童分别为4.52×10-8和2.53×10-7)则高于美国环境保护署推荐的范围。无论记录的相对安全指数如何,都需要采取预防措施来维持水生生态系统及其质量。必须作出努力,确保监测即使浓度很低也可能构成健康风险的重金属,并将其保持在尽可能低的水平,以确保安全和减少人类健康风险。
{"title":"POLLUTION EVALUATION AND HEALTH RISK ASSESSMENT OF HEAVY METALS IN STREAM WATER AT EAST AKIM MUNICIPAL ASSEMBLY, GHANA","authors":"Afua Amponsah Amankwah, Douglas Siaw Baah, E. Acheampong","doi":"10.26480/ecr.01.2022.15.22","DOIUrl":"https://doi.org/10.26480/ecr.01.2022.15.22","url":null,"abstract":"Water contamination with toxic chemicals such as heavy metals continue to rise globally and particularly in developing countries due to mining, urbanization, and industrialization. In this study, a total of 10 stream water samples were collected from the mining environment. Physicochemical parameters such as pH and heavy metals; arsenic (As), chromium (Cr), nickel (Ni), and lead (Pb) were examined using standard procedures. The study assessed heavy metals concentrations, evaluated the pollution indices, and the health risk (carcinogenic and non-carcinogenic) for the populace (both adult and child) through direct oral intake and dermal contact of stream water in East Akim Municipal Assembly. The results of the concentrations of As (0.114 mg/kg), Cr (0.00000605 mg/kg), Ni (0.025 mg/kg), and Pb (0.257 mg/kg) revealed that they were within acceptable limits prescribed by World Health Organization (WHO) and Water guidelines. Heavy metal evaluation index (HEI) and degree of contamination (Cd) values obtained indicated that all the examined samples were categorized as low (Cd < 1 and HEI < 10). Non-carcinogenic risk indicated that stream water consumption via ingestion and dermal pathways were below the oral reference dose for their respective heavy metals indicating that both age groups may be ingesting safe levels of heavy metals. Furthermore, the non-carcinogenic risk assessment suggest that children are more susceptible to health threats than adults considering both exposure pathways. Also, the hazard quotient and hazard index were < 1 inferring that there is a tolerable degree of non-carcinogenic health risk for both adults and children in the research area. In addition, average values (1.86×10-5 and 7.12×10-5 for adults and children) obtained for the assessment of cancer risk (CR) for CRingestion were within the safe range of 1×10-6 to 1×10-4 while CRdermal contact average values (4.52×10-8 and 2.53×10-7 for adults and children) were above the range recommended by US Environmental Protection Agency. Regardless of the relatively safe indices recorded, precautionary measures are necessary to sustain the aquatic ecosystem and its quality. Efforts must be made to ensure that heavy metals that can pose health risks even in their low concentrations are monitored and kept as low as possible to ensure safety and reduced human health risks.","PeriodicalId":11882,"journal":{"name":"ENVIRONMENTAL CONTAMINANTS REVIEWS","volume":"28 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73770688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
ORGANOPHOSPHATE AND CARBAMATE PESTICIDES RESIDUE ANALYSIS IN VEGETABLES PRODUCED IN FAR-WEST NEPAL 尼泊尔西部蔬菜中有机磷和氨基甲酸酯类农药残留分析
Pub Date : 2022-01-01 DOI: 10.26480/ecr.02.2022.69.71
Janaki Budha, Prativa Sapkota, A. Acharya, Rakshya Bhandari, Narendra B. Singh, D. Dhakal
This is an experimental research study carried out at the laboratory of wholesale fruits and vegetable market, Attarya, Kailali, to analyze organophosphate and carbamate pesticide residue in vegetables grown and marketed in four different districts of far-west Nepal by Rapid Bioassay of Pesticide Residue. The main goal of this study is to determine the proportion of AChE inhibition in various vegetable commodities and to compare the pesticide residue. Seven different vegetables were collected purposively from four distinct areas in Nepal’s far west region. Each of the 28 vegetable samples was analyzed for both organophosphate and carbamate residues. The sample was extracted from each vegetable and examined through a spectrophotometer and the data are interpreted. The experiment’s findings suggest that the Beans from Kanchanpur had the highest OP (21.69 percent) while cucumber from Dadeldhura had the lowest (0.07 percent). The bitter gourd of Kailali had the greatest C (24.39 percent), while the bottle gourd of Doti had the lowest (0.49 percent). All 56 items examined in the Attariya market laboratory were found to have low pesticide residue, with less than 35%. However, the waiting period must be strictly adhered to.
这是在Kailali Attarya水果和蔬菜批发市场实验室开展的一项实验性研究,目的是通过农药残留快速生物测定法分析尼泊尔远西部四个不同地区种植和销售的蔬菜中的有机磷和氨基甲酸酯农药残留。本研究的主要目的是确定各种蔬菜商品中乙酰胆碱酯酶的抑制比例,并对农药残留进行比较。从尼泊尔遥远的西部地区的四个不同地区有目的地收集了七种不同的蔬菜。对28份蔬菜样品中的每一份都进行了有机磷和氨基甲酸酯残留分析。从每一种蔬菜中提取样品,通过分光光度计进行检测,并对数据进行解释。实验结果表明,来自坎chanpur的豆子的OP最高(21.69%),而来自Dadeldhura的黄瓜最低(0.07%)。凯拉利苦瓜的C值最高(24.39%),多提葫芦最低(0.49%)。在Attariya市场实验室检查的56件产品均发现农药残留较低,低于35%。但是,必须严格遵守等待期。
{"title":"ORGANOPHOSPHATE AND CARBAMATE PESTICIDES RESIDUE ANALYSIS IN VEGETABLES PRODUCED IN FAR-WEST NEPAL","authors":"Janaki Budha, Prativa Sapkota, A. Acharya, Rakshya Bhandari, Narendra B. Singh, D. Dhakal","doi":"10.26480/ecr.02.2022.69.71","DOIUrl":"https://doi.org/10.26480/ecr.02.2022.69.71","url":null,"abstract":"This is an experimental research study carried out at the laboratory of wholesale fruits and vegetable market, Attarya, Kailali, to analyze organophosphate and carbamate pesticide residue in vegetables grown and marketed in four different districts of far-west Nepal by Rapid Bioassay of Pesticide Residue. The main goal of this study is to determine the proportion of AChE inhibition in various vegetable commodities and to compare the pesticide residue. Seven different vegetables were collected purposively from four distinct areas in Nepal’s far west region. Each of the 28 vegetable samples was analyzed for both organophosphate and carbamate residues. The sample was extracted from each vegetable and examined through a spectrophotometer and the data are interpreted. The experiment’s findings suggest that the Beans from Kanchanpur had the highest OP (21.69 percent) while cucumber from Dadeldhura had the lowest (0.07 percent). The bitter gourd of Kailali had the greatest C (24.39 percent), while the bottle gourd of Doti had the lowest (0.49 percent). All 56 items examined in the Attariya market laboratory were found to have low pesticide residue, with less than 35%. However, the waiting period must be strictly adhered to.","PeriodicalId":11882,"journal":{"name":"ENVIRONMENTAL CONTAMINANTS REVIEWS","volume":"25 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81675130","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
PAH EXPOSITION AND CARCINOGENICITY RISK EVALUATION IN SOILS FROM NIGER DELTA, NIGERIA 尼日利亚尼日尔三角洲土壤中多环芳烃暴露及致癌性风险评价
Pub Date : 2022-01-01 DOI: 10.26480/ecr.01.2022.35.39
K. Leizou, Gift Cornelius Timighe, M. Ashraf
Environmental pollution has become a cross-cutting issue in recent decades, garnering the attention of governments, governmental agencies, the general public, and scientific communities, and (PAHs) is one of the biggest hazards to public health. PAHs were evaluated in Niger Delta soils using a gas chromatography-mass spectrometry (GC-MS) technique to assess their distribution, exposure, and carcinogenicity risk. The SS1 location in the city had the highest amounts of PAH. The toxic equivalency factor (TEF), incremental lifetime cancer risk (ILCRs) and as well as a global comparison analysis was employed. The results showed that three city sample locations surpassed the clean-up standards for BaP, 0.1 mg/kg, according to the data. Carcinogenic polycyclic aromatic hydrocarbons (PAHs) are those polycyclic aromatic hydrocarbons (PAHs) determined as Group A (known human) and Group B (probable) carcinogens and currently seven PAHs classified probable human carcinogens (Group B2). The majority of the risk associated with PAHs is attributed to benzo (a) pyrene and a few other PAHs. The results further revealed that six out of the seven HMW PAHs are known human carcinogens. The results of this study were found to be within permissible levels recommended. However, the authors strongly advocate a remediation alternative aiming at decontaminating the PAH-polluted soils at SS1, SS3, and SS2.
近几十年来,环境污染已成为一个跨领域的问题,引起了政府、政府机构、公众和科学界的关注,而多环芳烃(PAHs)是公众健康的最大危害之一。采用气相色谱-质谱(GC-MS)技术对尼日尔三角洲土壤中的多环芳烃进行了评估,以评估其分布、暴露和致癌性风险。城市中SS1位置的多环芳烃含量最高。采用毒性当量因子(TEF)、终生癌症风险增量(ILCRs)以及全球比较分析。数据显示,三个城市样本地点的BaP超过了0.1 mg/kg的净化标准。致癌性多环芳烃(PAHs)是指被确定为A类(已知人类)和B类(可能)致癌物的多环芳烃(PAHs),目前有7种多环芳烃被分类为B2类(可能)人类致癌物。与多环芳烃相关的大部分风险归因于苯并(a)芘和其他一些多环芳烃。结果进一步显示,7种HMW多环芳烃中有6种是已知的人类致癌物。这项研究的结果被发现在允许的建议水平之内。然而,作者强烈主张对SS1、SS3和SS2的多环芳烃污染土壤进行净化修复。
{"title":"PAH EXPOSITION AND CARCINOGENICITY RISK EVALUATION IN SOILS FROM NIGER DELTA, NIGERIA","authors":"K. Leizou, Gift Cornelius Timighe, M. Ashraf","doi":"10.26480/ecr.01.2022.35.39","DOIUrl":"https://doi.org/10.26480/ecr.01.2022.35.39","url":null,"abstract":"Environmental pollution has become a cross-cutting issue in recent decades, garnering the attention of governments, governmental agencies, the general public, and scientific communities, and (PAHs) is one of the biggest hazards to public health. PAHs were evaluated in Niger Delta soils using a gas chromatography-mass spectrometry (GC-MS) technique to assess their distribution, exposure, and carcinogenicity risk. The SS1 location in the city had the highest amounts of PAH. The toxic equivalency factor (TEF), incremental lifetime cancer risk (ILCRs) and as well as a global comparison analysis was employed. The results showed that three city sample locations surpassed the clean-up standards for BaP, 0.1 mg/kg, according to the data. Carcinogenic polycyclic aromatic hydrocarbons (PAHs) are those polycyclic aromatic hydrocarbons (PAHs) determined as Group A (known human) and Group B (probable) carcinogens and currently seven PAHs classified probable human carcinogens (Group B2). The majority of the risk associated with PAHs is attributed to benzo (a) pyrene and a few other PAHs. The results further revealed that six out of the seven HMW PAHs are known human carcinogens. The results of this study were found to be within permissible levels recommended. However, the authors strongly advocate a remediation alternative aiming at decontaminating the PAH-polluted soils at SS1, SS3, and SS2.","PeriodicalId":11882,"journal":{"name":"ENVIRONMENTAL CONTAMINANTS REVIEWS","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74691043","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
SECONDARY DATA ANALYSIS ON PESTICIDE-GENE-DISEASE RELATIONS 农药-基因-疾病关系的二次资料分析
Pub Date : 2022-01-01 DOI: 10.26480/ecr.01.2022.09.14
E. M. Alvarenga, João Vitor Brito Oliveira, Mayara Sousa dos Santos, Júlia Naelly Machado Silva
Chemical pesticides can present toxic effects to human beings, and they are classified based on chemical characterization, presenting 300 active substances and more than 2000 different formulations. Their overuse can represent a significant risk factor to human health. Therefore, it is essential to investigate the putative association between health harms and pesticides because this information can be helpful for monitoring and controlling pesticide exposure. This study aims to analyze secondary data about pesticides and their effects on genes and disease phenotypes leading to health harm. For this, we used information about pesticides available on the Ministry of Agriculture, Livestock Breeding, and Supply documents. We also use the Set Analyzer tool available on the Comparative Toxicogenomics Database (CTD) to verify a putative association between pesticides and their specific chemical groups to human diseases. Finally, we use variance analysis to evaluate them for statistical purposes. Results showed that 127 chemical groups could be found in food, and they are classified into eight functional classes of pesticides used against pests in food crops. These functional classes are acaricides, bactericides, fungicides, herbicides, insecticides, molluscicides, nematicides, and plant growth regulators. Furthermore, data obtained from the CTD showed a predominance of digestive, nervous, respiratory, and skin diseases as the significant harms caused by pesticide exposure. Results also showed that all the pesticides’ functional classes affect genes associated with cancer development. Considering all the 127 chemical groups, we identified 145321 genes affected by these substances: 49733 genes affected by acaricides, 26832 genes affected by fungicides, 22687 genes affected by herbicides, 42681 genes affected by insecticides, 15842 genes affected by molluscicides, 15842 genes affected by nematicides, and 17217 genes affected by plant growth regulators. Organophosphates are the primary chemical group responsible for genetic effects, mainly leading to cancer and nervous system diseases. So, we conclude that seven different chemical groups can affect genes associated with cancer development and also concluded pesticide use could be related to genes effects and diseases development which can lead to health harms.
化学农药会对人类产生毒性作用,根据化学性质对其进行分类,有300种活性物质和2000多种不同的配方。它们的过度使用可能对人类健康构成重大风险因素。因此,有必要调查健康危害与农药之间可能存在的关联,因为这些信息有助于监测和控制农药暴露。本研究旨在分析农药及其对健康危害的基因和疾病表型的影响。为此,我们使用了农业、畜牧业和供应部文件中可获得的农药信息。我们还使用比较毒物基因组学数据库(CTD)上提供的Set Analyzer工具来验证农药及其特定化学组与人类疾病之间的假定关联。最后,出于统计目的,我们使用方差分析来评估它们。结果表明,食品中存在127个化学基团,可将其划分为8个功能类。这些功能类别是杀螨剂、杀菌剂、杀真菌剂、除草剂、杀虫剂、杀软体剂、杀线虫剂和植物生长调节剂。此外,从CTD获得的数据显示,农药暴露造成的重大危害主要是消化、神经、呼吸和皮肤疾病。结果还表明,所有农药的功能类别都影响与癌症发展相关的基因。综合127个化学类群,共鉴定出受这些物质影响的基因145321个,其中杀螨剂影响的基因49733个,杀真菌剂影响的基因26832个,除草剂影响的基因22687个,杀虫剂影响的基因42681个,杀螺剂影响的基因15842个,杀线虫剂影响的基因15842个,植物生长调节剂影响的基因17217个。有机磷酸盐是导致遗传效应的主要化学基团,主要导致癌症和神经系统疾病。因此,我们得出结论,七种不同的化学基团可以影响与癌症发展相关的基因,还得出结论,农药的使用可能与基因影响和疾病发展有关,从而导致健康危害。
{"title":"SECONDARY DATA ANALYSIS ON PESTICIDE-GENE-DISEASE RELATIONS","authors":"E. M. Alvarenga, João Vitor Brito Oliveira, Mayara Sousa dos Santos, Júlia Naelly Machado Silva","doi":"10.26480/ecr.01.2022.09.14","DOIUrl":"https://doi.org/10.26480/ecr.01.2022.09.14","url":null,"abstract":"Chemical pesticides can present toxic effects to human beings, and they are classified based on chemical characterization, presenting 300 active substances and more than 2000 different formulations. Their overuse can represent a significant risk factor to human health. Therefore, it is essential to investigate the putative association between health harms and pesticides because this information can be helpful for monitoring and controlling pesticide exposure. This study aims to analyze secondary data about pesticides and their effects on genes and disease phenotypes leading to health harm. For this, we used information about pesticides available on the Ministry of Agriculture, Livestock Breeding, and Supply documents. We also use the Set Analyzer tool available on the Comparative Toxicogenomics Database (CTD) to verify a putative association between pesticides and their specific chemical groups to human diseases. Finally, we use variance analysis to evaluate them for statistical purposes. Results showed that 127 chemical groups could be found in food, and they are classified into eight functional classes of pesticides used against pests in food crops. These functional classes are acaricides, bactericides, fungicides, herbicides, insecticides, molluscicides, nematicides, and plant growth regulators. Furthermore, data obtained from the CTD showed a predominance of digestive, nervous, respiratory, and skin diseases as the significant harms caused by pesticide exposure. Results also showed that all the pesticides’ functional classes affect genes associated with cancer development. Considering all the 127 chemical groups, we identified 145321 genes affected by these substances: 49733 genes affected by acaricides, 26832 genes affected by fungicides, 22687 genes affected by herbicides, 42681 genes affected by insecticides, 15842 genes affected by molluscicides, 15842 genes affected by nematicides, and 17217 genes affected by plant growth regulators. Organophosphates are the primary chemical group responsible for genetic effects, mainly leading to cancer and nervous system diseases. So, we conclude that seven different chemical groups can affect genes associated with cancer development and also concluded pesticide use could be related to genes effects and diseases development which can lead to health harms.","PeriodicalId":11882,"journal":{"name":"ENVIRONMENTAL CONTAMINANTS REVIEWS","volume":"11 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76424522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
PROFILE COMPOSITION AND RISK EVALUATION OF PAHS IN BOREHOLE WATER FROM AMASSOMA, BAYELSA STATE, NIGERIA 尼日利亚巴耶尔萨州阿马索马钻孔水中多环芳烃的剖面组成及风险评价
Pub Date : 2022-01-01 DOI: 10.26480/ecr.01.2022.23.30
K. Leizou, M. Ashraf
Water is an essential and indispensable natural resource. The most important to human endeavors, ecosystem and all living things. Thus, this study was carried out to determine the levels of concentration of sixteen (16) priority pollutants (PAHs) in borehole water from Amassoma, Bayelsa state. The PAH concentrations in the borehole water samples was performed using GC–MS method. The total PAHs concentration ranged from 0.003 – 0.364mg/l with a mean value of 0.132mg/l. Dibenzo(a,h)anthracene had the highest individual PAH concentration of 0.164mg/l. PAH accumulation in the environment and Toxic equivalency factor (TEF) used to estimate relative toxicity of a PAH compared to that of BaP, principal component analysis and pearson’s correlation was employed. Pearson correlation matrice analysis reveals a positive correlation between the PAHs; this could indicate a common source for some of the PAHs, however, some were negatively correlated with each other. This behavior could indicate non-point source. Six principal component accounting for 88% of the entire variance were extracted. A comparative analysis of PAHs concentrations in the water samples with maximum allowable concentration (MAC) standards revealed that the results obtained in this study were within the permissible levels except for Ind(1,2,3-cd) P and DbahA, however, carcinogen PAHs present in the water of the Amassoma axis, Nun River may pose a threat to human health. PAH fingerprint ratios for determining both petrogenic and pyrogenic (pyrolytic) PAH accumulation such as (Ant/(Ant+Phe), BaA/(BaA+Chr), and ∑▒〖LMW/∑▒HMW〗) ratios was employed. The PAH diagnostic ratio indicates that within the Amassoma Town was of mixed ratios, petroleum (petrogenic) and combustion (pyrogenic) sources and grass/wood/straw combustion sources. This is a clarion call on policy makers and necessary regulatory authorities to step up.
水是必不可少的自然资源。最重要的是人类的努力,生态系统和所有的生物。因此,本研究旨在确定巴耶尔萨州阿马索马钻孔水中16种优先污染物(多环芳烃)的浓度水平。采用气相色谱-质谱法测定钻孔水样中多环芳烃的浓度。多环芳烃总浓度范围为0.003 ~ 0.364mg/l,平均值为0.132mg/l。二苯并(a,h)蒽的个体PAH浓度最高,为0.164mg/l。多环芳烃在环境中的累积量和毒性等效因子(TEF)用于估计多环芳烃与BaP的相对毒性,采用主成分分析和pearson相关。Pearson相关矩阵分析结果表明,多环芳烃含量之间存在正相关关系;这可能表明一些多环芳烃有一个共同的来源,然而,一些多环芳烃彼此呈负相关。此行为可能表示非点源。提取了占总方差88%的6个主成分。通过对最大允许浓度(MAC)标准水样中多环芳烃(PAHs)浓度的对比分析,本研究得到的结果除Ind(1,2,3-cd) P和DbahA外,均在允许范围内,但在Nun河Amassoma轴水中存在的致癌物PAHs可能对人体健康构成威胁。采用(Ant/(Ant+Phe)、BaA/(BaA+Chr)、∑w /∑w〗比值等多环芳烃指纹图谱来测定岩石成因和热解成因的多环芳烃积累。多环芳烃诊断率表明,阿玛索马镇多环芳烃诊断率为石油(产岩)源和燃烧(热原)源以及草/木/秸秆燃烧源混合比例。这是对政策制定者和必要的监管机构加紧行动的响亮呼吁。
{"title":"PROFILE COMPOSITION AND RISK EVALUATION OF PAHS IN BOREHOLE WATER FROM AMASSOMA, BAYELSA STATE, NIGERIA","authors":"K. Leizou, M. Ashraf","doi":"10.26480/ecr.01.2022.23.30","DOIUrl":"https://doi.org/10.26480/ecr.01.2022.23.30","url":null,"abstract":"Water is an essential and indispensable natural resource. The most important to human endeavors, ecosystem and all living things. Thus, this study was carried out to determine the levels of concentration of sixteen (16) priority pollutants (PAHs) in borehole water from Amassoma, Bayelsa state. The PAH concentrations in the borehole water samples was performed using GC–MS method. The total PAHs concentration ranged from 0.003 – 0.364mg/l with a mean value of 0.132mg/l. Dibenzo(a,h)anthracene had the highest individual PAH concentration of 0.164mg/l. PAH accumulation in the environment and Toxic equivalency factor (TEF) used to estimate relative toxicity of a PAH compared to that of BaP, principal component analysis and pearson’s correlation was employed. Pearson correlation matrice analysis reveals a positive correlation between the PAHs; this could indicate a common source for some of the PAHs, however, some were negatively correlated with each other. This behavior could indicate non-point source. Six principal component accounting for 88% of the entire variance were extracted. A comparative analysis of PAHs concentrations in the water samples with maximum allowable concentration (MAC) standards revealed that the results obtained in this study were within the permissible levels except for Ind(1,2,3-cd) P and DbahA, however, carcinogen PAHs present in the water of the Amassoma axis, Nun River may pose a threat to human health. PAH fingerprint ratios for determining both petrogenic and pyrogenic (pyrolytic) PAH accumulation such as (Ant/(Ant+Phe), BaA/(BaA+Chr), and ∑▒〖LMW/∑▒HMW〗) ratios was employed. The PAH diagnostic ratio indicates that within the Amassoma Town was of mixed ratios, petroleum (petrogenic) and combustion (pyrogenic) sources and grass/wood/straw combustion sources. This is a clarion call on policy makers and necessary regulatory authorities to step up.","PeriodicalId":11882,"journal":{"name":"ENVIRONMENTAL CONTAMINANTS REVIEWS","volume":"29 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87585794","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
期刊
ENVIRONMENTAL CONTAMINANTS REVIEWS
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1