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引用次数: 2

摘要

高分子基质中含有无机材料的杂化膜是一类质子导电杂化电解质。以聚乙烯醇(PVA)、四乙氧基硅烷(TEOS)和杂多酸(HPA)为原料,制备了质子交换膜燃料电池(pemfc)用无机/有机导电膜。采用傅里叶变换红外光谱(FTIR)、x射线衍射光谱(XRD)、扫描电镜(SEM)和热重分析(TGA)对合成的杂化膜进行了表征。研究了杂多酸掺入对膜性能的影响,包括膜的形态和热稳定性。
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Proton-conducting PVA/PMA Hybrid Membranes for Fuel Cell Applications
The hybrid membranes containing inorganic materials in polymer matrix are identified as a remarkable family of proton conducting hybrid electrolytes. In this work, the proton conducting inorganic/organic hybrid membranes for proton exchange membrane fuel cells (PEMFCs) were prepared using polyvinyl alcohol (PVA), tetraethoxyorthosilane (TEOS) and heteropolyacid (HPA). The synthesized hybrid membranes were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction spectroscopy (XRD), Scanning electron microscopy (SEM) and Thermogravimetry analysis (TGA). The effects of heteropolyacid incorporation on membrane properties, including morphology and thermal stability were extensively investigated.
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