Liang Jia, Li Duo Wang, Jing Li, Jun Xiang, Yi Chen, H. Fan
{"title":"表面粗糙的二氧化硅嵌入聚脲微球,用于哑光皮革整理","authors":"Liang Jia, Li Duo Wang, Jing Li, Jun Xiang, Yi Chen, H. Fan","doi":"10.34314/jalca.v117i5.4913","DOIUrl":null,"url":null,"abstract":"A type of polyurea microspheres with rough surfaces and different sizes (1-12 μm), which was used for waterborne polyurethane matte leather coating, were prepared by precipitation polymerization in H 2 O/acetonitrile system, using isophorone diisocyanate as polymerized monomer, 2,4-diaminobenzenesulfonic acid sodium salt as hydrophilic monomer and nano-SiO 2 as surface roughener. The effect of the loading of isophorone diisocyanate and 2,4-diaminobenzenesulfonic acid sodium salt, the volume ratio of H 2 O/acetonitrile and the addition stage of nano-SiO 2 on the particle size and surface roughness were investigated so as to achieve the excellent matte effect of the coating. The results indicated that the adding of hydrophilic monomer can reduce the particle size of microspheres and improve its re-dispersibility in water, while the increase of the proportion of acetonitrile in the mixed solvent and the loading of polymerized monomer can enlarge the size of the polyurea microspheres. As surface roughener, with the increase of nano-SiO 2 loading, the surface roughness and the particle size of microspheres increase. When nano-SiO 2 is added at the stage of the reaction system getting turbid, the maximum surface roughness of polyurea microspheres can be achieved. Polyurea microspheres with particle size (1-2 μm) and high surface roughness have better matting effect, and the gloss of the prepared waterborne polyurethane coating can be adjusted to less than 1.6° (60°-incident Angle).","PeriodicalId":17201,"journal":{"name":"Journal of The American Leather Chemists Association","volume":null,"pages":null},"PeriodicalIF":0.6000,"publicationDate":"2022-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Silica-Embedded Polyurea Microspheres with Rough Surface for Matte Leather Finishing\",\"authors\":\"Liang Jia, Li Duo Wang, Jing Li, Jun Xiang, Yi Chen, H. Fan\",\"doi\":\"10.34314/jalca.v117i5.4913\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A type of polyurea microspheres with rough surfaces and different sizes (1-12 μm), which was used for waterborne polyurethane matte leather coating, were prepared by precipitation polymerization in H 2 O/acetonitrile system, using isophorone diisocyanate as polymerized monomer, 2,4-diaminobenzenesulfonic acid sodium salt as hydrophilic monomer and nano-SiO 2 as surface roughener. The effect of the loading of isophorone diisocyanate and 2,4-diaminobenzenesulfonic acid sodium salt, the volume ratio of H 2 O/acetonitrile and the addition stage of nano-SiO 2 on the particle size and surface roughness were investigated so as to achieve the excellent matte effect of the coating. The results indicated that the adding of hydrophilic monomer can reduce the particle size of microspheres and improve its re-dispersibility in water, while the increase of the proportion of acetonitrile in the mixed solvent and the loading of polymerized monomer can enlarge the size of the polyurea microspheres. As surface roughener, with the increase of nano-SiO 2 loading, the surface roughness and the particle size of microspheres increase. When nano-SiO 2 is added at the stage of the reaction system getting turbid, the maximum surface roughness of polyurea microspheres can be achieved. Polyurea microspheres with particle size (1-2 μm) and high surface roughness have better matting effect, and the gloss of the prepared waterborne polyurethane coating can be adjusted to less than 1.6° (60°-incident Angle).\",\"PeriodicalId\":17201,\"journal\":{\"name\":\"Journal of The American Leather Chemists Association\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2022-04-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The American Leather Chemists Association\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.34314/jalca.v117i5.4913\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The American Leather Chemists Association","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.34314/jalca.v117i5.4913","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Silica-Embedded Polyurea Microspheres with Rough Surface for Matte Leather Finishing
A type of polyurea microspheres with rough surfaces and different sizes (1-12 μm), which was used for waterborne polyurethane matte leather coating, were prepared by precipitation polymerization in H 2 O/acetonitrile system, using isophorone diisocyanate as polymerized monomer, 2,4-diaminobenzenesulfonic acid sodium salt as hydrophilic monomer and nano-SiO 2 as surface roughener. The effect of the loading of isophorone diisocyanate and 2,4-diaminobenzenesulfonic acid sodium salt, the volume ratio of H 2 O/acetonitrile and the addition stage of nano-SiO 2 on the particle size and surface roughness were investigated so as to achieve the excellent matte effect of the coating. The results indicated that the adding of hydrophilic monomer can reduce the particle size of microspheres and improve its re-dispersibility in water, while the increase of the proportion of acetonitrile in the mixed solvent and the loading of polymerized monomer can enlarge the size of the polyurea microspheres. As surface roughener, with the increase of nano-SiO 2 loading, the surface roughness and the particle size of microspheres increase. When nano-SiO 2 is added at the stage of the reaction system getting turbid, the maximum surface roughness of polyurea microspheres can be achieved. Polyurea microspheres with particle size (1-2 μm) and high surface roughness have better matting effect, and the gloss of the prepared waterborne polyurethane coating can be adjusted to less than 1.6° (60°-incident Angle).
期刊介绍:
The Journal of the American Leather Chemists Association publishes manuscripts on all aspects of leather science, engineering, technology, and economics, and will consider related subjects that address concerns of the industry. Examples: hide/skin quality or utilization, leather production methods/equipment, tanning materials/leather chemicals, new and improved leathers, collagen studies, leather by-products, impacts of changes in leather products industries, process efficiency, sustainability, regulatory, safety, environmental, tannery waste management and industry economics.