化学活化粉末生物吸附剂对铅的吸附研究

M. Meriatna, L. Hakim, M. Masrullita, Zulmiardi Zulmiardi, Suri Atika
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摘要

环境中的重金属污染现在非常令人担忧,如果进入人体是危险的。人体与重金属铅(Pb)的持续相互作用将导致各种健康问题。尼帕棕榈是一种棕榈(Palma),生长在红树林栖息地或沿海地区,纤维素含量为35.1%,半纤维素含量为26.4%,木质素含量为17.8%。这项研究的目的是看看棕榈叶是否可以作为生物吸附剂来去除人工溶液中的重金属铅。分析分阶段进行,首先从尼帕树叶中提取生物吸附剂,将其缩小成粉末并在阳光下晒干,然后使用FTIR仪器分析生物吸附剂的功效和官能团的数量。采用Langmuir和Freundlich等温方程方法,通过改变nipa棕榈叶吸附剂的粒径,即40、60和80目,以及接触时间为30、60、90和100分钟,来确定吸附水平和吸附机理。使用的铅溶液浓度为20ppm。结果表明,在粒径为80目、接触时间为100分钟时,金属吸收率最高达99.29%。吸附机理接近Langmuir等温线方程,R2 = 0.9998。怀疑吸附过程发生在吸附剂的一层(单层)中。
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Study of Adsorption of Lead Metal (Pb) Using Chemically Acti-vated (Nypa Fruticans) Powder Biosorbent
Heavy metal contamination in the environment is now quite concerning, and it is hazardous if it enters the body. Continuous human interaction with heavy metal lead (Pb) will result in various health problems. Nipa palm is a palm (Palma) thrives in mangrove forest habitats or along the seashore, with a cellulose content of 35.1%, 26.4% hemicellulose, and 17.8% lignin. This research aims to see if palm fronds (Nypa fruticans) can be used as a biosorbent to remove the heavy metal Pb in artificial solutions. The analysis was carried out in phases, beginning with the creation of biosorbents from Nipah fronds by decreasing their size to powder and drying them in the sun, followed by analyzing the efficacy of the biosorbents and the number of functional groups using the FTIR instrument. The research was carried out by varying the particle size of the nipa palm frond adsorbent, namely 40, 60, and 80 mesh, as well as contact times of 30, 60, 90, and 100 minutes, to determine the level of adsorption absorption and the adsorption mechanism using the Langmuir and Freundlich isotherm equation approach. The Pb solution used had a concentration of 20 ppm. The results showed that the maximum metal absorption level was 99.29% at a particle size of 80 mesh with a contact time of 100 minutes. The absorption mechanism is close to the Langmuir isotherm equation with R2 = 0.9998. It is suspected that the adsorption process occurs in one layer (monolayer) of the adsorbent.
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