聚乙烯空间电荷分布的直接观察

T. Mizutani, Y. Suzuoki, T. Furuta, M. Ieda, T. Suzuki
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引用次数: 12

摘要

采用激光诱导压力脉冲(LIPP)技术和压电诱导压力阶跃(PIPS)波技术研究了PE(聚乙烯)中的空间电荷行为。所用样品为名义上不含添加剂的25 μ m厚薄膜和0.6 mm和1 mm厚的低密度PE板。LIPP测量在333 K下极化15分钟,然后在室温下短路的光谱上进行。PIPS测量是在25 μ m厚的样品上进行的。在高场下,PE体中存在正空间电荷,而电子注入引起的负空间电荷占主导地位。PE的氧化增强了电子和空穴的注入。
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Direct observation of space charge distribution in polyethylene
The space charge behavior in PE (polyethylene) was investigated using the laser-induced pressure pulse (LIPP) technique and the piezoelectrically induced pressure step (PIPS) wave technique. Specimens used were 25- mu m-thick films and 0.6- and 1-mm-thick plates of low-density PE nominally free from additives. The LIPP measurement was carried out on a spectrum which was polarized at 333 K for 15 min and subsequently short-circuited at room temperature. The PIPS measurement was carried out on a 25- mu m-thick specimen under an applied field. Positive space charge was found to exist in the PE bulk, and negative space charge due to electron injection was dominant at high fields. Oxidation of PE was found to enhance electron and hole injection.<>
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