天然染料中单宁类化合物的研究

P. Paryanto, S. H. Pranolo, A. Susanti, Bintang Timur Putrikatama, I. R. Qatrunada, Angga Dwi Wibowo
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引用次数: 0

摘要

一般来说,用于纺织材料的天然染料是从植物的提取物中提取的,如根、木、叶、种子和花。纺织工业特别是蜡染工匠,已经知道许多植物可以染色纺织材料,如靛蓝(indigofera), soga tingi树皮(Ceriops tagal), tegeran木(Cudraina javanensis),姜黄(Curcuma),茶(The), noni根(Morinda citrifelia), soga jambal树皮(Pelthophorum ferruginum), kesumba (Bixa orelana)和番石榴叶(Psidiumguajava)。之所以选择刺荆树皮,是因为它可以产生单宁,可以用作天然染料。本研究的目的是定性和定量地测定苦荞皮中单宁的含量。采用红外光谱法和高效液相色谱法进行分析。用傅里叶红外光谱法测定了槐树树皮提取物中所含化合物的含量。通过FTIR分析可以看出,在3375、13 cm-1的波数中存在O-H和N-H基团。C=O键,波数为1739,16 cm-1。C=C键,波数为1624,31 cm-1。波数为2970 72 cm-1 1456 39 cm-1和1365 74 cm-1的C-H键。波数为1365的NO2键,74 cm-1。波数为1228,69 cm-1和1217,34 cm-1的C-N键。碳氧键的波数是1228 69 cm-1 1217 34 cm-1和1052,3 cm-1。同时采用高效液相色谱法测定了刺荆树皮提取物中单宁含量。高效液相色谱条件:流速:1ml /min,流动相:MeOH: H2O (50:50), λ: 271 nm,柱:C18, 250 mm。通过高效液相色谱分析得知,黄芪树皮提取物中单宁含量为22,44 ppm。
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Tannins Compound In Soga Tingi Bark (Ceriops Tagal) As Natural Dyes

In general, natural dyes for textile materials are obtained from extracts part of the plants such as roots, wood, leaves, seeds, and flower. Textile industry especially batik craftsman, have known many plants that can dye textile materials, such as indigo (indigofera), soga tingi bark (Ceriops tagal), tegeran wood (Cudraina javanensis), turmeric (Curcuma), tea (The), noni root (Morinda citrifelia), soga jambal bark (Pelthophorum ferruginum), kesumba (Bixa orelana), and guava leaf (Psidiumguajava). Soga tingi bark chosen because it can produce tannins which can be used as natural dyes. The purpose of this research was to obtained tannin content in soga tingi bark as qualitatively and quantitatively. The analysis carried out is FTIR and HPLC method. FTIR analysis carried out to determine of the compounds contained in the soga tingi bark extraction. Based on FTIR analysis it can be seen that there are O-H and N-H group in the wavenumber 3375,13 cm-1. C=O bond at wavenumber 1739,16 cm-1. C=C bond at wavenumber 1624,31 cm-1. C-H bond at wavenumbers 2970,72 cm-1, 1456,39 cm-1, and 1365,74 cm-1. NO2 bond at wavenumber 1365,74 cm-1. C-N bond at wavenumbers 1228,69 cm-1 and 1217,34 cm-1. And C-O bond at wavenumbers 1228,69 cm-1, 1217,34 cm-1, and 1052,3 cm-1. While HPLC analysis carried out to determine contains tannin level in the soga tingi bark extraction. HPLC conditions used are Flowrate: 1 mL/min, Mobile phase: MeOH : H2O (50:50), λ: 271 nm and Column: C18, 250 mm. Based on HPLC analysis it is known that the contains tannin level in the soga tingi bark extraction is 22,44 ppm.

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