{"title":"2,6-二硝基-4- x -苯胺- n -甲基丙酰胺:与甲氧基钾的反应","authors":"J. Boulton, P. Jewess, N. R. Mcfarlane","doi":"10.1039/J29710000928","DOIUrl":null,"url":null,"abstract":"The interactions between potassium methoxide and compounds of the type 2,6-dinitro-4-substituted anilinopropionamides (I) have been studied kinetically over a range of temperatures in methanol. The formation of a Meisenheimer complex is shown to occur with σ-bond formation at the 1-position of the aniline and the reasons for the observation of this path rather than anilino N–H ionization or 3-σ complex formation are discussed.","PeriodicalId":17268,"journal":{"name":"Journal of The Chemical Society B: Physical Organic","volume":"161 1","pages":"928-930"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"2,6-Dinitro-4-X-anilino-N-methylpropionamides: reactions with potassium methoxide\",\"authors\":\"J. Boulton, P. Jewess, N. R. Mcfarlane\",\"doi\":\"10.1039/J29710000928\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The interactions between potassium methoxide and compounds of the type 2,6-dinitro-4-substituted anilinopropionamides (I) have been studied kinetically over a range of temperatures in methanol. The formation of a Meisenheimer complex is shown to occur with σ-bond formation at the 1-position of the aniline and the reasons for the observation of this path rather than anilino N–H ionization or 3-σ complex formation are discussed.\",\"PeriodicalId\":17268,\"journal\":{\"name\":\"Journal of The Chemical Society B: Physical Organic\",\"volume\":\"161 1\",\"pages\":\"928-930\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society B: Physical Organic\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J29710000928\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society B: Physical Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J29710000928","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
2,6-Dinitro-4-X-anilino-N-methylpropionamides: reactions with potassium methoxide
The interactions between potassium methoxide and compounds of the type 2,6-dinitro-4-substituted anilinopropionamides (I) have been studied kinetically over a range of temperatures in methanol. The formation of a Meisenheimer complex is shown to occur with σ-bond formation at the 1-position of the aniline and the reasons for the observation of this path rather than anilino N–H ionization or 3-σ complex formation are discussed.
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