直流蒸汽发生器(OTSG)管失效分析

Wahida Tina, Elizabeth Donaldson, Thomas E. Dickinson, W. Schmidt
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引用次数: 0

摘要

一次性蒸汽发生器(OTSG)使用纯化的给水产生过热蒸汽。工厂特定的水质,蒸汽质量,高温和高压操作导致OTSG管泄漏,具有经济,安全和环境后果。管道泄漏是OTSG管道故障最常见的原因之一。在110兆瓦热电联产厂的OTSG装置内发现了泄漏管。坏掉的管子从蒸汽发生器上拆了下来。对该管段进行了多次冶金检查,以确定失效模式和原因。用光学发射光谱(OES)分析了部分管的合金成分。结果证实,该管由符合ASME规范SB 407 Inconel Alloy 800 (UNS N08800)化学规格的材料制造。采用玻璃爆丸法测定沉积重量密度(DWD)。DWD值最大为5.1 g/ft2。最大内部沉积厚度为0.002 in。没有观察到过热的迹象。利用扫描电子显微镜-能量色散x射线分析(SEM-EDXA)确定了内部沉积物的元素组成。结果表明,内部灰质沉积物主要由铁、铬和镍化合物组成。钠、硅、铝、钾和钙的含量也更少。主体管的破坏涉及到一个贯穿壁的裂纹,发生应力腐蚀开裂(SCC)。OTSG水处理实践中使用的苛性碱溶液的添加可能会诱导腐蚀性物质进入管中。
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Failure Analysis of Once-Through Steam Generator (OTSG) Tube
The once-through steam generator (OTSG) produces superheated steam using purified feed water. The plant-specific water quality, steam quality, high temperature, and pressure operations lead to the leakage of the OTSG tubes with economic, safety, and environmental consequences. Tube leakage is one of the most frequent causes of OTSG tube failure. A leaking tube was discovered within the OTSG unit of the 110 MW cogeneration plant. The failed section of the tube was removed from the steam generator. Several metallurgical examinations of this tube segment were performed to identify the failure mode and cause. A portion of the tube was analyzed using optical emission spectroscopy (OES) to determine the alloy composition. The results confirmed that the tubing was fabricated from a material consistent with chemical specifications for ASME Specification SB 407 Inconel Alloy 800 (UNS N08800). Glass bead blasting was used to determine the deposit-weight-density (DWD). The DWD value was a maximum of 5.1 g/ft2. The maximum internal deposit thickness was 0.002 in. No evidence of overheating was observed. Scanning electron microscope-energy-dispersive x-ray analysis (SEM-EDXA) was used to determine the elemental composition of the internal deposits. The results indicated that the internal gray deposits primarily comprised iron, chromium, and nickel compounds. There were also fewer amounts of sodium, silicon, aluminum, potassium, and calcium species. The subject tube failure involved a through-wall crack that occurred as stress corrosion cracking (SCC). Additions of caustic solution used in OTSG water treatment practices potentially induced corrosive substances into the tube.
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