合成纳米氧化锌在工业废水中黄色碱性染料净化中的应用

H. S. Hassan, M. Elkady, M. Abbas, A. Atalla
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摘要

以三乙醇胺(TEA)为表面活性剂,采用水热法,以氨水还原氯化锌盐,成功合成了氧化锌纳米棒。利用x射线粉末衍射(XRD)、扫描电子显微镜(SEM)和傅里叶变换红外光谱(FTIR)等不同的表征技术对所制备材料的性能进行了测定。结果表明:制备的ZnO在pH = 10时呈棒状。采用合成的纳米棒氧化锌作为吸附剂对工业废水中的碱性黄28染料进行脱色。合成的纳米zno在60min内的染料脱色亲和度达到93.26%。采用间歇法研究了不同工艺参数对染料吸附过程的影响。染料溶液pH和温度的增加与脱色过程的下降有关。纳米氧化锌的最佳用量为10 g/L。采用Langmuir、Freundlich和Temkin平衡等温线分析了平衡吸附数据。实验结果证实了合成的纳米氧化锌作为吸附剂用于废水染料净化的适用性。关键词:纳米氧化锌,染料脱色,吸附参数。
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Utilization of Synthesized Nano-Zinc Oxide in Yellow Basic Dye Decontamination from Industrial Wastewater
ZnO nanorod has been successfully synthesized through the reduction of Zinc chloride salt with ammonia solution in the presence of triethanolamine (TEA) as surfactant agent via hydrothermal technique. The properties of the produced material were determined using different characterization techniques such as X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and Fourier Transform Infrared spectrum (FTIR). The results showed that the asprepared ZnO are rod- like morphologies at pH equal to 10. The synthesized nano rod-zinc oxide was employed as adsorbent agent for basic yellow 28 dye decolorization from polluted industrial wastewater. The synthesized nano-ZnO was achieved 93.26% dye decolorization affinity with in 60minutes. The variation in the different processing parameters on the dye sorption process was elucidated using batch technique. The increment in both the dye solution pH and its temperature was association with decline in the decolourization process. The optimum nano-zinc oxide dosage was recorded to be equal to 10 g/L. The adsorption data at equilibrium were analyzed using Langmuir, Freundlich and Temkin equilibrium isotherms. The experimental results confirmed the applicability of synthesized nano-zinc oxide as adsorbent agent for dye decontamination from polluted wastewater. Keywords: nano-zinc oxide, dye decolourization, sorption parameters.
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