棕榈基生物油升级生产第二代生物柴油:过程模拟技术研究

M. D. Solikhah, H. P. Putra, A. Prismantoko, A. Kismanto, G. W. Murti, T. Araki, H. Nabetani
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摘要

面对日益增长的能源消耗,生物柴油已成为克服化石燃料资源有限的柴油替代燃料的有利燃料。然而,FAME生物柴油的使用目前仅限于混合30%。因此,有必要考虑其他燃料作为柴油的替代品。其中之一是开发第二代生物柴油,这种生物柴油是由生物油经过热解升级而产生的。生物油可通过加氢加工和催化裂化两大工艺升级为纯石脑油燃料。从油棕生物质中生产生物油的技术经济研究已经进行了研究,但尚未包括升级生物油的技术经济研究。在进行技术经济研究之前,有必要选择生物油升级的工艺技术路线。因此,需要从油棕基生物油的升级换代入手,进行产业研究和第二代生物柴油生产技术的比较,得出最优的工艺流程图。利用ChemCad软件进行了工艺模拟,得到了物料平衡和能耗比。这项工作估计了从19台60吨/小时的棕榈油磨坊收集的棕榈残留物生产的生物燃料。生物油投入70.35吨/小时,升级油收率为32.21%。该模型的产能率为35.7%,所需能量为76.5 MMJ/h。该过程所需的能源可以通过与棕榈油生产工厂相连的综合燃料升级设施提供,可以提供自我可持续的生产设施。
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Second Generation Biodiesel Production from Upgrading of Palm-Based Bio-Oil: Technology Study through Process Simulation
Biodiesel has become favorable fuel for diesel fuel substitute to overcome the limited fossil fuel resources while facing the increasing of energy consumption. However, the use of FAME biodiesel is currently limited to mixing up to 30%. Therefore, it is necessary to consider other fuels as an alternative to diesel oil. One of them is by developing second generation biodiesel, which produced from the upgrading process of bio-oil as a result of pyrolysis. Bio-oil can be upgraded to fuel with range naphtha through two main processes that consisted of hydro-processing and catalytic cracking. Techno-economic studies on bio-oil production from oil palm biomass have been studied but the techno-economic studies up to upgraded bio-oil have not included. Before a techno-economic study was carried out, it was necessary to select the process technology route of upgrading bio-oil. Therefore, it is required to conduct a study of industry and the comparison of second generation biodiesel production technology from the upgrading of oil palm-based bio-oil to obtain an optimum process flow diagram. Process simulations were conducted using ChemCad software so that the mass balance and ratio of energy consumption was obtained. This work estimated the biofuel produced from palm residues collected from 19 units of a 60 tons/hour palm oil mill. The bio-oil input is 70.35 tons/hours with upgrading oil yield of 32.21%. The energy yield of this model is 35.7% while required 76.5 MMJ/hour of the energy. The energy required for this process can be provided by an integrated fuel upgrading facilities that connected with the palm bio-oil production plant could provide self-sustainable production facilities.
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