{"title":"氧化钛酸盐(V)配合物Na2[(TcVO)(OTf)5]·2(TfOH)与TfOH =三氟甲烷磺酸的晶体结构","authors":"Markus Zegke, Aida Raauf, J. Neudörfl, E. Strub","doi":"10.1515/znb-2022-0143","DOIUrl":null,"url":null,"abstract":"Abstract The autoreduction of ammonium pertechnetate in solutions of trifluoromethanesulfonic acid (triflic acid, TfOH) and trifluoromethanesulfonic anhydride (triflic anhydride, TfOTf) results, in the presence of sodium ions, in the formation of the complex Na2[(TcVO)(OTf)5] · 2(TfOH). Its structure has been determined by single-crystal X-ray diffraction.","PeriodicalId":23831,"journal":{"name":"Zeitschrift für Naturforschung B","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2023-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Crystal structure of the oxidotechnetate(V) complex Na2[(TcVO)(OTf)5] · 2(TfOH) with TfOH = trifluoromethanesulfonic acid\",\"authors\":\"Markus Zegke, Aida Raauf, J. Neudörfl, E. Strub\",\"doi\":\"10.1515/znb-2022-0143\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract The autoreduction of ammonium pertechnetate in solutions of trifluoromethanesulfonic acid (triflic acid, TfOH) and trifluoromethanesulfonic anhydride (triflic anhydride, TfOTf) results, in the presence of sodium ions, in the formation of the complex Na2[(TcVO)(OTf)5] · 2(TfOH). Its structure has been determined by single-crystal X-ray diffraction.\",\"PeriodicalId\":23831,\"journal\":{\"name\":\"Zeitschrift für Naturforschung B\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-05-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeitschrift für Naturforschung B\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1515/znb-2022-0143\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift für Naturforschung B","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/znb-2022-0143","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Crystal structure of the oxidotechnetate(V) complex Na2[(TcVO)(OTf)5] · 2(TfOH) with TfOH = trifluoromethanesulfonic acid
Abstract The autoreduction of ammonium pertechnetate in solutions of trifluoromethanesulfonic acid (triflic acid, TfOH) and trifluoromethanesulfonic anhydride (triflic anhydride, TfOTf) results, in the presence of sodium ions, in the formation of the complex Na2[(TcVO)(OTf)5] · 2(TfOH). Its structure has been determined by single-crystal X-ray diffraction.
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