EP/ srtio3和EP/ batio3纳米复合材料热电性能的比较研究

Hao Wen, Lin Cheng, Yi Jiang, Taiyun Zhu, Zhong Chen
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摘要

本文分别采用srtio3和batio3纳米粒子作为填料制备了EP/ srtio3和epibatio3纳米复合材料。研究了复合材料的导热系数、介电谱、击穿强度和闪络特性。结果表明,在相同质量分数下,EP/ srtio3纳米复合材料的导热系数和介电常数均高于EP/ batio3纳米复合材料。由于纳米颗粒在环氧树脂基体中的均匀分布,EP/ srtio3和EP/ batio3纳米复合材料的击穿场强均随着填料质量分数的增加而提高。此外,纳米颗粒的掺入有助于修复环氧树脂内部的潜在缺陷,从而形成更致密、更光滑的结构。在微秒脉冲电压下对样品表面进行的闪络实验证明,纳米复合材料的闪络电压高于纯环氧树脂。EP/ srtio3的闪络电压略高于EP/BaTiO3。综上所述,填充srtio3或batio3纳米颗粒可以提高环氧树脂的导热性和绝缘性能,特别是闪络电压显著提高。这种新型复合材料将为储能材料和多功能介电材料的发展奠定基础。
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Comparative study on thermal and electrical properties of EP/SrTiO3and EP/BaTiO3nanocomposites
In this paper, the EP/SrTiO3and EPIBaTiO3nanocomposite were prepared by adopting SrTiO3or BaTiO3nanoparticles as fillers respectively. Thermal conductivity, dielectric spectrum, breakdown strength and flashover characteristics of the composites were investigated. The results reveal thermal conductivity and dielectric constant of EP/SrTiO3nanocomposite are higher than that of EP/BaTiO3nanocomposite with the same mass fraction. Owing to uniform distribution of nanoparticles in the epoxy resin matrix, both EP/SrTiO3and EP/BaTiO3nanocomposite have an improved breakdown field strength which increase with the mass fraction of filler. Moreover, incorporation of nanoparticles can help repair the potential defects inside the epoxy resin, creating a denser and smoother structure. Flashover experiment on the surface of sample under the microsecond pulse voltage proves that the flashover voltages of the nanocomposite are higher than that of the pure epoxy resin. Flashover voltages of EP/SrTiO3are slightly higher than that of EP/BaTiO3. To draw a conclusion, filling SrTiO3or BaTiO3nanoparticles can improve the thermal conductivity and insulating property of epoxy resin, especially the flashover voltage increases significantly. The novel composite would lay a foundation for the development of energy storage material and multifunctional dielectric material.
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