新型大豆和葡萄籽油基聚合物的合成和热研究:利用绿色化学原理的清洁高效途径

M. V. D. Almeida, R. Alarcon, G. Bannach
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引用次数: 3

摘要

以大豆籽、葡萄籽等植物油为原料,根据绿色化学原理合成了甘油聚合物。同时热重分析-差热分析(TG-DTA)和差示扫描量热法(DSC)评估了热分解、热稳定性、氧化、玻璃化转变和结晶过程。因此,有可能验证它们在接近室温时发生玻璃化转变。因此,这些聚合物可用于诸如由温度和热安全标签触发的化学缓释剂。
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Synthesis and thermal studies of new soybean and grape seed oil-based polymers: Clean and efficient pathway using green Chemistry principles
This paper describes the synthesis of polymers from glycerol and vegetable oils as soybean and grape seed, synthesized following the principles of Green Chemistry. Simultaneous Thermogravimetric Analysis – Differential Thermal Analysis (TG-DTA) and Differential Scanning Calorimetry (DSC) were employed to evaluate the thermal decomposition, thermal stability, oxidation, glass transition and crystallization processes. Hence it was possible to verify that they have glass transition near to room temperature. Therefore these polymers may be used such as chemical slow release agents triggered by temperature and thermal security tags.
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